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Mademuasel [1]
2 years ago
10

The heat of vaporization for benzaldehyde is 48.8 kj/mol, and its normal boiling point is 451.0 k. use this information to deter

mine benzaldehyde's vapor pressure (in torr) at 61.5°c. report your answer to three significant digits.
Chemistry
1 answer:
user100 [1]2 years ago
7 0

Answer:

The vapor pressure of benzaldehyde at 61.5 °C is 70691.73 torr.

Explanation:

  • To solve this problem, we use Clausius Clapeyron equation: ln(P₁/P₂) = (ΔHvap / R) (1/T₁ - 1/T₂).
  • The first case: P₁ = 1 atm = 760 torr and T₁ = 451.0 K.
  • The second case: P₂ = <em>??? needed to be calculated</em> and T₂ = 61.5 °C = 334.5 K.
  • ΔHvap = 48.8 KJ/mole = 48.8 x 10³ J/mole and R = 8.314 J/mole.K.
  • Now, ln(P₁/P₂) = (ΔHvap / R) (1/T₁ - 1/T₂)
  • ln(760 torr /P₂) = (48.8 x 10³ J/mole / 8.314 J/mole.K) (1/451 K - 1/334.5 K)
  • ln(760 torr /P₂) = (5869.62) (-7.722 x 10⁻⁴) = -4.53.
  • (760 torr /P₂) = 0.01075
  • Then, P₂ = (760 torr) / (0.01075) = 70691.73 torr.

So, The vapor pressure of benzaldehyde at 61.5 °C is 70691.73 torr.

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In this case, for the considered reaction, it is clear it is an exothermic reaction because it produces energy; and therefore, the higher the temperature the more reactants are yielded as the reverse reaction is favored. Moreover, since the effect of pressure is verified as favoring the side with fewer moles; in this case the products side (2 moles of ammonia).

In such a way, the high pressure favors the formation of ammonia whereas the high temperature the formation of hydrogen and nitrogen and therefore, option A is ruled out. Since the high pressure shifts the reaction rightwards and the high temperature leftwards, we would not be able to know whether the reaction has ended or not because it will be a "go and come back" process, that is why B is also discarded. Now, since hydrogen and nitrogen would be the "wastes", we discard C because they are not toxic. That is why the most accurate answer would be D. because it is actually true that such equipment is quite expensive.

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