Answer: 1-Phenyl ethyl radical is formed as an intermediate in the reaction and since Phenyl ethyl radical has a trigonal planar geometry so it is a planar molecule having two faces. So Br radical radical can recombine with the two faces with equal probability leading to a racemic mixture in 50:50ratio of products.Hence two products are formed which are known as enatiomers.
Explanation:
When we irradiate the ethylbenzene with UV light , it leads to homolytic cleavage and 1- Phenyl ethyl free radical is generated.
Phenyl ethyl free radical is generated because it is very stable as it is on a secondary carbon center as well as on a benzylic position so it can be stabilized by the resonance as well as inductive effect at the secondary carbon center.
NBS(N-bromosuccinimide) is a source of bromine radical and provides bromine free radical.
Once the 1- Phenyl ethyl free radical is generated then bromine free radical can recombine with benzyl free radical leading to product formation.
Since 1- Phenyl ethyl free radical has a trigonal planar geometry so it is a planar molecule which has two faces and hence the radical recombination with bromine free radical can occur with either of the two faces available.
Kindly refer the attachments for structure as well as the mechanism of the reaction.
So two isomers which are enantiomers are produced are obtained.
Answer:
A) mass divided by volume
Explanation:
(i) We start by calculating the mass of sugar in the solution:
mass of sugar = concentration × solution mass
mass of sugar = 2.5/100 × 500 = 12.5 g
Then now we can calculate the amount of water:
solution mass = mass of sugar + mass of water
mass of water = solution mass - mass of sugar
mass of water = 500 - 12.5 = 487.5 g
(ii) We use the following reasoning:
If 500 g solution contains 12.5 g sugar
Then X g solution contains 75 g sugar
X=(500×75)/12.5 = 3000 g solution
Now to get the amount of solution in liters we use density (we assume that is equal to 1):
Density = mass / volume
Volume = mass / density
Volume = 3000 / 1 = 3000 liters of sugar solution