Consider the reaction. S⥫⥬????2????1P What effects are produced by an enzyme on the general reaction? The rate constant for the
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Using the VSPER theory, the effect of lone pairs on molecular shape can be discussed.
There are 3 types of electron pairs present in a molecular shape: bond pair -bond pair, lone pair - bond pair, lone pair - lone pair.
Strength of repulsions between these three types of pair follows the order:
lone pair- lone pair > lone pair - bond pair > bond pair - bond pair
Whenever there is an addition of lone pairs to the geometry, some distortions take place which decreases the bond angles and some asymmetry is attained in the original molecular shape.
Answer:
34,6g of (NH₄)₂SO₄
Explanation:
The boiling-point elevation describes the phenomenon in which the boiling point of a liquid increases with the addition of a compound. The formula is:
ΔT = kb×m
Where ΔT is Tsolution - T solvent; kb is ebullioscopic constant and m is molality of ions in solution.
For the problem:
ΔT = 109,7°C-108,3°C = 1,4°C
kb = 1.07 °C kg/mol
Solving:
m = 1,31 mol/kg
As mass of X = 600g = 0,600kg:
1,31mol/kg×0,600kg = 0,785 moles of ions. As (NH₄)₂SO₄ has three ions:
0,785 moles of ions× = 0,262 moles of (NH₄)₂SO₄
As molar mass of (NH₄)₂SO₄ is 132,14g/mol:
0,262 moles of (NH₄)₂SO₄× = <em>34,6g of (NH₄)₂SO₄</em>
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I hope it helps!