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nexus9112 [7]
3 years ago
9

One liter of a buffer contains 2.00 Molar NaA and 2.00 Molar HA. (A- is the anion of an acid) 15.00 g NaOH is added. (Assume no

volume change) What is the new pH?
HA (aq) + H2O (l) A - (aq) + H3O+ (aq) Ka = 2.3 x 10-11
Chemistry
1 answer:
madam [21]3 years ago
3 0

Answer:

The new pH is 10.8031

Explanation:

Given information:

[NaA] = concentration = 2 M

[HA] = concentration = 2 M

V = volume = 1 L

15 g of NaOH added

Question: What is the new pH, pH = ?

Moles of NaA:

n_{NaA} =2\frac{moles}{L} *1L=2moles

Moles of HA:

n_{HA} =2\frac{moles}{L} *1L=2moles

Moles of NaOH:

n_{NaOH} =15g*\frac{1mol}{40g} =0.375moles

The reaction:

HA + NaOH → NaA + H₂O

Moles of NaA = 2 + 0.375 = 2.375 moles

Moles of HA = 2 - 0.375 = 1.625 moles

The value of Ka is 2.3x10⁻¹¹

The pKa:

pKa=-logKa=-log(2.3x10^{-11} )=10.6383

Applying the Henderson's Hasselbach equation

pH=pKa+log\frac{molesNaA}{molesHA} =10.6383+log\frac{2.375}{1.625} =10.8031

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the half life of a certain element is 100 days. how many half-lives will it be before only one-fourth of this element reamains
Rama09 [41]

Answer:

200 Days

Explanation:

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Say we start with 100 grams.  After the amount of time for the half life to pass completes, we have 50, or half of the original amount.  The half life time passes again and THAT gets cut in half to 25 grams.  this is 1/4 of the original (Hey, what we're looking for.)  Just to make it clear what is happening after another half life 1/8 remains, so it goes from The starting amount to 1/2 to 1/4 to 1/8 and so on, it keeps getting cut in half.

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4 0
3 years ago
The Haber Process is the main industrial procedure to produce ammonia. The reaction combines nitrogen from air with hydrogen mai
Firdavs [7]

Answer:

A) N_2(g)+3H_2(g)\rightleftharpoons 2NH_3(g).

B) Kc=0.0933.

C) 0.9 mol.

D) Increasing both temperature and pressure.

Explanation:

Hello,

In this case, given the information, we proceed as follows:

A)

N_2(g)+3H_2(g)\rightleftharpoons 2NH_3(g)

B) For the calculation of Kc, we rate the equilibrium expression:

Kc=\frac{[NH_3]^2}{[N_2][H_2]^3}

Next, since at equilibrium the concentration of ammonia is 0.6 M (0.9 mol in 1.5 dm³ or L), in terms of the reaction extent x, we have:

[NH_3]=0.6M=2*x

x=\frac{0.6M}{2}=0.3M

Next, the concentrations of nitrogen and hydrogen at equilibrium are:

[N_2]=\frac{1.5mol}{1.5L}-x=1M-0.3M=0.7M

[H_2]=\frac{4mol}{1.5L}-3*x=2.67M-0.9M=1.77M

Therefore, the equilibrium constant is:

Kc=\frac{(0.6M)^2}{(0.7M)*(1.77M)^3}\\ \\Kc=0.0933

C) In this case, the equilibrium yield of ammonia is clearly 0.9 mol since is the yielded amount once equilibrium is established.

D) Here, since the reaction is endothermic (positive enthalpy change), one way to increase the yield of ammonia is increasing the temperature since heat is reactant for endothermic reactions. Moreover, since this reaction has less moles at the products, another way to increase the yield is increasing the pressure since when pressure is increased the side with fewer moles is favored.

Best regards.

7 0
3 years ago
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