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lisabon 2012 [21]
4 years ago
15

If I apply 0.108 kJ of energy in order to increase the temperature of a bar of gold from 30.0°C to 34.7°C, and the specific heat

capacity of gold is 0.128 J/g°C, what is the mass the bar of gold in grams? A. 1.8 × 102 g B. 6.5 × 101 g C. 1.08 × 102 g D. 1.28 × 102 g E. none of these
Chemistry
1 answer:
Alex4 years ago
4 0

Answer:

The mass of the given gold bar:<u> m = 1.8 × 10² g</u>

Explanation:

The Specific heat capacity (c) of a given substance is defined as the heat capacity (C) per unit mass (m) or the energy required (Q) to increase the temperature (ΔT) of the given substance per unit mass.

∴ <u>The specific heat capacity</u>: c = \frac{C}{m} =\frac{Q}{m\times \Delta T}

Given: The specific heat capacity of gold (Au) = 0.128 J/g°C

The increase in temperature: ΔT = 34.7°C - 30.0°C = 4.7°C

Heat energy: Q = 0.108 kJ = 0.108 × 1000 J = 108 J    (∵ 1 kJ = 1000J)

Mass of the given gold bar: m = ?

<u>Therefore, the mass of the given gold bar</u>:

m = \frac{Q}{c\times \Delta T}

m = \frac{108 J}{(0.128 J/g.^{\circ }C)\times (4.7 ^{\circ }C)}

m = 179.5 g = 1.795\times 10^{2} g

\therefore m \approx 1.8 \times 10^{2} g

<u>Therefore, the mass of the given gold bar: m = 1.8 × 10² g</u>

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Brut [27]

Answer:

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5 0
3 years ago
Consider the titration of a 20.0 mL sample of 0.500 M HCN (Ka =6.17x10-10) with 0.250 M KOH. a. (6pt) What is the initial pH? b.
Salsk061 [2.6K]

Answer:

a. pH = 4.75

b. pH = 9.20

c. pH = 8.42

d. pH = 13.53

Explanation:

This is a titration between a strong base, the KOH and a weak acid, HCN.

The initial pH is the pH, when you did not add the base yet, so it is the pH of the HCN

          HCN + H2O ⇄  H₃O⁺  +  CN⁻

Initial    0.5                      -             -

Eq.      0.5-x                    x             x

Ka =  x² / (0.5-x) = 6.17ₓ10⁻¹⁰

Ka is really small, so we can say that 0.5-x = 0.5. Then,

x² = 6.17ₓ10⁻¹⁰ . 0.5

x = √(6.17ₓ10⁻¹⁰ . 0.5) = 1.75×10⁻⁵ → [H₃O⁺]

pH = - log [H₃O⁺]  →  - log 1.75×10⁻⁵ = 4.75

b. First of all, we determine the moles of base, we are adding.

0.250 mol/L . 0.006 L = 0.0015 moles

In conclussion we have 0.0015 moles of OH⁻

Now, we determine the moles of our acid.

0.500 mol/L . 0.020L = 0.01 moles

The  0.0015 moles of OH⁻ will be neutralized with the acid, so:

      HCN     +    OH⁻         →     H₂O   +    CN⁻

       0.01         0.0015                          0.0085

The hydroxides are neutralized with the proton from the weak acid, so we have 0.0085 moles of cyanide and 0.0085 moles of HCN. (0.01-0.0015)

Our new volume is 20 mL and 6mL that we added, so, 26mL

This is a buffer with the weak acid, and its conjugate base.

Our concentrations are 0.0085 moles / 0.026 L = 0.327 M

We apply Henderson-Hasselbach

pH = pKa + log (base/acid) → pH = 9.20 + log (0.327/0.327)

pH = pKa

c. When we add 40 mL, our volume is 20mL +40mL  = 60 mL

These are the moles, we add:

0.040 L . 0.250 mol/L = 0.01 moles of KOH (moles of OH⁻)

 HCN     +    OH⁻         →     H₂O   +    CN⁻

  0.01          0.01                                 0.01

All the hydroxides have neutralized all the moles from the HCN, so we only have in solution, cyanhide. This is the equivalence point.

0.01 moles / 0.060 L = 0.16 M → [CN⁻]

pH at this point will be

       CN⁻  +  H₂O ⇄  HCN + OH⁻             Kb = 1.62ₓ10⁻⁵ (Kw/Ka)

In.   0.16                        -          -

Eq. 0.16-x                     x          x

Kb = x² / (0.16-x)

We can also assume that 0.16-x = 0.16. Then:

[OH⁻] = √(Kb . 0.16) → √(1.62ₓ10⁻⁵ .  0.16) = 2.59×10⁻⁶

- log [OH⁻] = pOH → - log 2.59×10⁻⁶ = 5.58

pH = 14 - pOH  → 14 - 5.58 = 8.42

This is a basic pH, because the titration is between a weak acid and a strong base.

d. When we add 42 mL of base, our volume is 20mL + 42 mL = 62 mL

We add 0.5 mol/L . 0.062L = 0.031 moles

These are the moles of OH⁻ , so as we have neutralized all the acid with 40 mL, with 42 mL of base, we only have base in solution.

0.031 moles - 0.01 moles = 0.021 moles of OH⁻

[OH⁻] = 0.021 moles / 0.062L = 0.34M

- log [OH⁻]  = pOH → - log 0.34 = 0.47

pH = 14-pH → 14 - 0.47 = 13.53

8 0
3 years ago
A solution is known to contain either Ni2 or Cr3 . Addition of what single (1 only) reagent would identify which ion is present?
galina1969 [7]

Answer:

Explanation:

From the periodic table; both elements given are from the same group 3.

To test for which ion will be present in the experiment;

We added 6M aqueous sodium hydroxide  in excess.

This process is followed by the addition of hydrogen peroxide H2O2 while stirring.

Heat is then applied to the solution.

After we've carried out those process;

We will notice the following;

IfNi^{2+} is present, then a green NI(OH)_2  precipitate will be formed

If Cr^{3+} is present,then a yellow-colored CrO^{2-}_{4} will be formed.

6 0
3 years ago
An aqueous solution was created by placing 0.018 g of NaCl into a 50 mL volumetric flask and diluting to volume with deionized w
Burka [1]

Answer:

Molarity: 6.2x10⁻³M NaCl

Molality: 6.2x10⁻³m NaCl

Mole Fraction: 1.1x10⁻⁴

Mass% NaCl: 0.036% (m/m NaCl)

Explanation:

<em>Molarity -Moles NaCl / L-</em>

<em>Moles NaCl -Molar mass: 58.44g/mol-</em>

0.018g * (1mol/58.44g) = <em>0.000308 moles NaCl</em>

<em>Liters water:</em>

50mL * (1L/1000mL) = <em>0.050L</em>

M = 0.000308 moles NaCl / 0.050L

<h3>M = 6.2x10⁻³M NaCl</h3><h3 />

<em>Molality -Moles NaCl / kg water-</em>

<em>Moles NaCl = 0.000308 moles NaCl</em>

<em>kg water = 50mL * (1g/mL) * (1kg/1000g) = 0.050kg</em>

m = 0.000308 moles NaCl / 0.050kg

<h3>m = 6.2x10⁻³m NaCl</h3><h3 />

<em>Mole Fraction -Moles NaCl / Moles water+ Moles NaCl-</em>

<em>Moles water = 50g * (1mol/18.01g) = 2.776 moles</em>

Moles fraction = 0.000308 moles NaCl / 0.000308 moles NaCl + 2.776moles water

<h3>Mole fraction = 1.1x10⁻⁴</h3><h3 />

<em>Mass Percent -Mass NaCl / Mass NaCl+Mass Water * 100</em>

0.018g / 50g+0.018g * 100

<h3>0.036% (m/m NaCl)</h3>

<em />

8 0
3 years ago
Which change increases the amount of iron produced in the equation fe3o4(s) 4h2(g) energy?
Debora [2.8K]
FeSO4 (s) plus  4H2 (g) gives  3Fe(s)  plus  4H2O(l)
  from  the  equation  above   i  mole  of  FeSO4 reacted  with  4  mole  of H2  gas  to  give  3 moles  of  iron  and  4  moles  of  water.There  is  a relationship  between  volume  and  equilibrium  shift. Decrease  in  volume  favor  the  side  with  less  moles  of  a  gas. since  hydrogen  is  a  gas    a  decrease  in   volume  favor  the  forward  reaction  hence  more  Fe  is  produced.
6 0
3 years ago
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