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andrezito [222]
4 years ago
8

A brine solution of salt flows at a constant rate of 9 ​L/min into a large tank that initially held 100 L of brine solution in w

hich was dissolved 0.1 kg of salt. The solution inside the tank is kept well stirred and flows out of the tank at the same rate. If the concentration of salt in the brine entering the tank is 0.02 ​kg/L, determine the mass of salt in the tank after t min. When will the concentration of salt in the tank reach 0.01 ​kg/L?
Chemistry
1 answer:
Valentin [98]4 years ago
4 0

Answer:

a) C = 0.02 - ((e ⁻ ⁽⁹ᵗ ⁺ ¹•⁷⁶⁶⁾)/9)

b) The concentration of salt in the tank attains the value of 0.01 kg/L at time, t = 0.0713 min = 4.28s

Explanation:

Taking the overall balance, since the total Volume of the setup is constant, then flowrate in = flowrate out

Let the concentration of salt in the tank at anytime be C

Let the Concentration of salt entering the tank be Cᵢ

Let the concentration of salt leaving the tank be C₀ = C (Since it's a well stirred tank)

Let the flowrate in be represented by Fᵢ

Let the flowrate out = F₀ = F

Fᵢ = F₀ = F

Then the component balance for the salt

Rate of accumulation = rate of flow into the tank - rate of flow out of the tank

dC/dt = FᵢCᵢ - FC

Fᵢ = 9 L/min, Cᵢ = 0.02 kg/L, F = 9 L/min

dC/dt = 0.18 - 9C

dC/(0.18 - 9C) = dt

∫ dC/(0.18 - 9C) = ∫ dt

(-1/9) In (0.18 - 9C) = t + k

In (0.18 - 9C) = -9t - 9k

-9k = K

In (0.18 - 9C) = K - 9t

At t = 0, C = 0.1/100 = 0.001 kg/L

In (0.18 - 9(0.001)) = K

In 0.171 = K

K = - 1.766

So, the equation describing concentration of salt at anytime in the tank is

In (0.18 - 9C) = -1.766 - 9t

In (0.18 - 9C) = - (9t + 1.766)

0.18 - 9C = e ⁻ ⁽⁹ᵗ ⁺ ¹•⁷⁶⁶⁾

9C = 0.18 - (e ⁻ ⁽⁹ᵗ ⁺ ¹•⁷⁶⁶⁾)

C = 0.02 - ((e ⁻ ⁽⁹ᵗ ⁺ ¹•⁷⁶⁶⁾)/9)

b) when C = 0.01 kg/L

0.01 = 0.02 - ((e ⁻ ⁽⁹ᵗ ⁺ ¹•⁷⁶⁶⁾)/9)

0.09 = (e ⁻ ⁽⁹ᵗ ⁺ ¹•⁷⁶⁶⁾)

- (9t + 1.766) = In 0.09

- (9t + 1.766) = -2.408

(9t + 1.766) = 2.408

9t = 2.408 - 1.766 = 0.642

t = 0.642/9 = 0.0713 min = 4.28s

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Determine the equilibrium constant, Kp, for the following reaction, by using the two reference equations below: 2 NO(g) + O2(g)
klio [65]

Answer:

Kp=3.07x10^6

Explanation:

Hello,

In this case, by knowing the given reference reactions, one could rearrange them as follows:

2 NO(g) \leftrightarrow N_2(g) + O_2(g); Kp_2 = \frac{1}{2.3 x 10^{-19}}=4.35x10^{18}

N_2(g) + 2O_2(g) \leftrightarrow 2NO_2(g);Kp_3=(8.4x10^{-7})^2=7.056x10^{-13}

Subsequently, to obtain the main reaction, we add the aforementioned reference rearranged reactions as shown below (just as reference):

2NO(g)+N_2(g)+2O_2\leftrightarrow 2NO_2(g)+N_2+O_2

Consequently, the equilibrium constant is computed as:

Kp=\frac{[N_2][O_2]}{[NO]^2} * \frac{[NO_2]^2}{[N_2][O_2]^2} =Kp_2*Kp_3=4.35x10^{18}*7.056x10^{-13}=3.07x10^6

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8 0
3 years ago
What is the limiting reagent when a 2.00 g sample of ammonia is mixed with 4.00 g of oxygen?​
UNO [17]

Answer:

Ammonia is limiting reactant

Amount of oxygen left  = 0.035 mol

Explanation:

Masa of ammonia = 2.00 g

Mass of oxygen = 4.00 g

Which is limiting reactant = ?

Balance chemical equation:

4NH₃ + 3O₂     →     2N₂ + 6H₂O

Number of moles of ammonia:

Number of moles = mass/molar mass

Number of moles = 2.00 g/ 17 g/mol

Number of moles = 0.12 mol

Number of moles of oxygen:

Number of moles = mass/molar mass

Number of moles = 4.00 g/ 32 g/mol

Number of moles = 0.125 mol

Now we will compare the moles of ammonia and oxygen with water and nitrogen.

                      NH₃          :            N₂

                        4             :             2

                      0.12           :           2/4×0.12 = 0.06

                      NH₃         :            H₂O

                        4            :             6

                        0.12       :           6/4×0.12 = 0.18

                       

                       O₂            :            N₂

                        3             :             2

                      0.125        :           2/3×0.125 = 0.08

                        O₂           :            H₂O

                        3              :             6

                        0.125       :           6/3×0.125 = 0.25

The number of moles of water and nitrogen formed by ammonia are less thus ammonia will be limiting reactant.

Amount of oxygen left:

                        NH₃          :             O₂

                           4            :              3

                           0.12       :          3/4×0.12= 0.09

Amount of oxygen react = 0.09 mol

Amount of oxygen left  = 0.125 - 0.09 = 0.035 mol

3 0
3 years ago
If 21.00 mL of a 0.68 M solution of C6H5NH2 required 6.60 mL of the strong acid to completely neutralize the solution, what was
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Answer:

pH = 2.46

Explanation:

Hello there!

In this case, since this neutralization reaction may be assumed to occur in a 1:1 mole ratio between the base and the strong acid, it is possible to write the following moles and volume-concentrations relationship for the equivalence point:

n_{acid}=n_{base}=n_{salt}

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n_{salt}=0.021L*0.68mol/L=0.01428mol

So we can divide those moles by the total volume (0.021L+0.0066L=0.0276L) to obtain the concentration of the final salt:

[salt]=0.01428mol/0.0276L=0.517M

Now, we need to keep in mind that this is an acidic salt since the base is weak and the acid strong, so the determinant ionization is:

C_6H_5NH_3^++H_2O\rightleftharpoons  C_6H_5NH_2+H_3O^+

Whose equilibrium expression is:

Ka=\frac{[C_6H_5NH_2][H_3O^+]}{C_6H_5NH_3^+}

Now, since the Kb of C6H5NH2 is 4.3 x 10^-10, its Ka is 2.326x10^-5 (Kw/Kb), we can also write:

2.326x10^{-5}=\frac{x^2}{0.517M}

Whereas x is:

x=\sqrt{0.517*2.326x10^{-5}}\\\\x=3.47x10^-3

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pH=-log(3.47x10^{-3})\\\\pH=2.46

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6 0
3 years ago
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miv72 [106K]

Answer:

hope this help by the way found off of yahoo

Explanation:

Calculate the number of grams of nitrogen dioxide that are produced from

4 moles of nitric oxide.

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4NO(g) + 2O2(g) ->4NO2(g) please help and explain i want to learn this

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