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andrezito [222]
4 years ago
8

A brine solution of salt flows at a constant rate of 9 ​L/min into a large tank that initially held 100 L of brine solution in w

hich was dissolved 0.1 kg of salt. The solution inside the tank is kept well stirred and flows out of the tank at the same rate. If the concentration of salt in the brine entering the tank is 0.02 ​kg/L, determine the mass of salt in the tank after t min. When will the concentration of salt in the tank reach 0.01 ​kg/L?
Chemistry
1 answer:
Valentin [98]4 years ago
4 0

Answer:

a) C = 0.02 - ((e ⁻ ⁽⁹ᵗ ⁺ ¹•⁷⁶⁶⁾)/9)

b) The concentration of salt in the tank attains the value of 0.01 kg/L at time, t = 0.0713 min = 4.28s

Explanation:

Taking the overall balance, since the total Volume of the setup is constant, then flowrate in = flowrate out

Let the concentration of salt in the tank at anytime be C

Let the Concentration of salt entering the tank be Cᵢ

Let the concentration of salt leaving the tank be C₀ = C (Since it's a well stirred tank)

Let the flowrate in be represented by Fᵢ

Let the flowrate out = F₀ = F

Fᵢ = F₀ = F

Then the component balance for the salt

Rate of accumulation = rate of flow into the tank - rate of flow out of the tank

dC/dt = FᵢCᵢ - FC

Fᵢ = 9 L/min, Cᵢ = 0.02 kg/L, F = 9 L/min

dC/dt = 0.18 - 9C

dC/(0.18 - 9C) = dt

∫ dC/(0.18 - 9C) = ∫ dt

(-1/9) In (0.18 - 9C) = t + k

In (0.18 - 9C) = -9t - 9k

-9k = K

In (0.18 - 9C) = K - 9t

At t = 0, C = 0.1/100 = 0.001 kg/L

In (0.18 - 9(0.001)) = K

In 0.171 = K

K = - 1.766

So, the equation describing concentration of salt at anytime in the tank is

In (0.18 - 9C) = -1.766 - 9t

In (0.18 - 9C) = - (9t + 1.766)

0.18 - 9C = e ⁻ ⁽⁹ᵗ ⁺ ¹•⁷⁶⁶⁾

9C = 0.18 - (e ⁻ ⁽⁹ᵗ ⁺ ¹•⁷⁶⁶⁾)

C = 0.02 - ((e ⁻ ⁽⁹ᵗ ⁺ ¹•⁷⁶⁶⁾)/9)

b) when C = 0.01 kg/L

0.01 = 0.02 - ((e ⁻ ⁽⁹ᵗ ⁺ ¹•⁷⁶⁶⁾)/9)

0.09 = (e ⁻ ⁽⁹ᵗ ⁺ ¹•⁷⁶⁶⁾)

- (9t + 1.766) = In 0.09

- (9t + 1.766) = -2.408

(9t + 1.766) = 2.408

9t = 2.408 - 1.766 = 0.642

t = 0.642/9 = 0.0713 min = 4.28s

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What volumes of 0.200 M HCOOH and 2.00 M NaOH would make 500. mL of a buffer with the same pH as one made from 475 mL of 0.200 M
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<u>36 ml of NaOh and</u><u> 464 ml</u><u> of </u><u>HCOOH</u><u> would be enough to form 500 ml of a buffer with the same pH as the buffer made with </u><u>benzoic acid </u><u>and NaOH.</u>

What is benzoic acid found in?

  • Some natural sources of benzoic acid include: ​Fruits:​ Apricots, prunes, berries, cranberries, peaches, kiwi, bananas, watermelon, pineapple, oranges.
  • ​Spices:​ Cinnamon, cloves, allspice, cayenne pepper, mustard seeds, thyme, turmeric, coriander.

Calculate the amount of moles in NaOH and benzoic acid. This calculation is done by multiplying molarity by volume.

Amount of moles of NaOH -2 × 0.025 =  0.05 mol

Amount of moles of benzoic acid 2 × 0.475 = 0.095 mol

In this case, we can calculate the pH produced by the buffer of these two reagents, as follows

pH = pKa + log\frac{base}{acid}

4.2 + log\frac{0.05}{0.045} = 4.245

We must repeat this calculation, with the values shown for HCOOH and NaOH. In this case, we can calculate as follows

pH = pKa + log\frac{base}{acid}

4.245 = 3.75 + log\frac{base}{acid}

log\frac{base}{acid} = 0.5

\frac{base}{acid} = 3.162

Now we must solve the equation above. This will be done using the following values

\frac{2(0.5 - x)}{0.2x - 2(0.5 - x)} = 0.464 L

With these values, we can calculate the volumes of NaOH and HCOOH needed to make the buffer.

NaOH volume

( 0.5 - 0.464)L

0.036L .................... 36ml

HCOOH volume

500 - 36 = 464mL

Learn more about benzoic acid

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