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Irina-Kira [14]
3 years ago
7

Usually potassium hydrogen phthalate is kept very pure. But Stu Dent thinks the bottle of potassium hydrogen phthalate has been

accidently mixed with sodium chloride salt. He decides to use a titration to determine the amount of potassium hydrogen phthalate present. He weighs 2.3854 g of the contaminated potassium hydrogen phthalate mixture. The titration uses 17.47 mL of 0.5000 M sodium hydroxide. Use the titration volume and concentration to calculate the moles of potassium hydrogen phthalate actually reacted. Then use the molar mass (204.2 g/mol) to calculate the mass of potassium hydrogen phthalate actually reacted. Enter the mass to 4 significant digits with units of g.
Chemistry
1 answer:
Ahat [919]3 years ago
5 0

Answer:

1.784 g

Explanation:

The equation of the reaction is;

NaOH(aq) + KHC8H4O4(aq) --------> KNaC8H4O4(aq) + H2O(l)

Number of moles of NaOH reacted = 17.47/1000 * 0.5000 M

Number of moles of NaOH reacted =8.735 * 10^-3 moles

From the reaction equation;

1 mole of NaOH reacted with 1 mole of KHC8H4O4

Hence, 8.735 * 10^-3 moles of NaOH reacts with 8.735 * 10^-3 moles of KHP.

So,

Mass of KHP reacted = 8.735 * 10^-3 moles * 204.2 g/mol = 1.784 g

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<img src="https://tex.z-dn.net/?f=H_2PO_4%5E-%28aq%29%20%5Crightarrow%20H%5E%2B%28aq%29%20%2B%20HPO_4%5E%7B2-%7D%28aq%29" id="Te
klasskru [66]

Answer:

The pH of the buffer solution = 8.05

Explanation:

Using the Henderson - Hasselbalch equation;

pH = pKa₂ + log ( [HPO₄²-]/[H₂PO4⁻]

where pKa₂ = -log (Ka₂) = -log ( 6.1 * 10⁻⁸) = 7.21

Concentration of OH⁻ added = 0.069 M (i.e. 0.069 mol/L)

[H₂PO4⁻] after addition of OH⁻ = 0.165 - 0.069 = 0.096 M

[HPO₄²-] after addition of OH⁻ = 0.594 + 0.069 = 0.663 M

Therefore,

pH = 7.21 + log (0.663 / 0.096)

pH = 7.21 + 0.84

pH = 8.05

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