Answer:
kf = 1.16 x 10¹⁸
Explanation:
Step 1: [Ni(H₂O)₆]²⁺ + 1en → [Ni(H₂O)₄(en)]²⁺ ΔG°1 = -42.9 kJmol⁻¹
Step 2: [Ni(H₂O)₄(en)]²⁺ + 1en → [Ni(H₂O)₂(en)₂]²⁺ ΔG°2 = -35.8 kJmol⁻¹
Step 3: [Ni(H₂O)₂(en)₂]²⁺ + 1en → [Ni(en)₃]²⁺ ΔG°3 = -24.3 kJmol⁻¹
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Overall reaction: [Ni(H₂O)₆]²⁺ + 3en → [Ni(en)₃]²⁺ ΔG°r
ΔG°r = ΔG°1 + ΔG°2 + ΔG°3
ΔG°r = -42.9 - 35.8 - 24.3
ΔG°r = -103.0 kJmol⁻¹
ΔG°r = -RTlnKf
-103,000 Jmol⁻¹ = - 8.31 J.K⁻¹mol⁻¹ x 298 K x lnKf
kf = e ^(-103,000/-8.31x298)
kf = e ^41.59
kf = 1.16 x 10¹⁸
Answer:
Ratio is 3:2
3CO = 2Fe or 1.5 CO = 1 Fe
Explanation:
Fe2O3 + 3CO = 2Fe + 3CO2
Fe2O3 = Iron (|||) oxide
CO = Carbon monoxide
Fe = Solid Iron
CO2 = Carbon dioxide
Excellent is already balanced.
10 Moles Fe and 15 Moles of CO2
5 Moles Fe2O3 + 15 Moles 3CO = 10 Moles Fe + 15 Moles 3CO2
What is the ratio of carbon monoxide to solid iron
Ratio is 3:2 or 1.5 CO = 1 Fe
Here we apply the Clausius-Clapeyron equation:
ln(P₁/P₂) = ΔH/R x (1/T₂ - 1/T₁)
The normal vapor pressure is 4.24 kPa (P₁)
The boiling point at this pressure is 293 K (P₂)
The heat of vaporization is 39.9 kJ/mol (ΔH)
We need to find the vapor pressure (P₂) at the given temperature 355.3 K (T₂)
ln(4.24/P₂) = 39.9/0.008314 x (1/355.3 - 1/293)
P₂ = 101.2 kPa
Answer:
Genetic equilibrium is the state in which allele frequencies do
not change in a generation over generation.
Explanation:
Genetic equilibrium can be described as a situation which arises when a certain allele or genotype remains constant for a species generation over generations. Genetic equilibrium can be maintained if no external factors like mutations affect the population of the species. The phenomenon of natural selection and evolution need to be stopped if a genetic equilibrium is to be maintained. Hardy-Weinberg theorem is the mathematical depiction of genetic equilibrium.
Answer: penetration is the ability of an electron in a given orbital to approach the nucleus closely. Shielding refers to the fact that core electrons reduce the degree of nuclear attraction felt by the orbital electrons. Shielding is the opposite of penetration. The most penetrating orbital is the least screening orbital. The order of increasing shielding effect/decreasing penetration is s<p<d<f.
Explanation:
The order of penetrating power is 1s>2s>2p>3s>3p>4s>3d>4p>5s>4d>5p>6s>4f....
Since the 3p orbital is more penetrating than the 3d orbital, it will lie nearer to the nucleus and thus possess lower energy.
