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Snowcat [4.5K]
3 years ago
11

A particular graduated cylinder contains 24.0 mL Br2(liquid). The density of bromine at 25 degrees C is 3.12g/cm^3. Note that in

nature, elemental bromine exists in diatomic form(that is, as Br2)
How many representative particles(molecules of Br2) are in the cylinder?
Chemistry
1 answer:
motikmotik3 years ago
4 0

Answer:

2.82x10^{23}molecules

Explanation:

Hello.

In this case, given the volume (1cm³=1mL) and density of the bromine we are to firstly compute the mass since it will allow us to compute the representative particles:

\rho =\frac{m}{V}

m=\rho *V=3.12g/cm^3*24.0cm^3\\\\m=74.88gBr_2

Next, since the mass of one mole of diatomic bromine is 159.82 g (one bromine weights 78.91), we can next compute the moles in that sample:

n=74.88g*\frac{1mol}{159.82g} =0.469molBr_2

Finally, via the Avogadro's number we can compute the representative particles of bromine as follows:

particles=0.469mol*\frac{6.022x10^{23}molecules}{1mol}\\ \\2.82x10^{23}molecules

Best regards.

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<u>Answer:</u>

<u>For a:</u> The mass of acetic anhydride needed is 73.91 grams.

<u>For b:</u> The theoretical yield of aspirin is 130.43 grams.

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To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}   .....(1)

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Given mass of salicylic acid = 1.00\times 10^2g=100g

Molar mass of salicylic acid = 138.121 g/mol

Putting values in equation 1, we get:

\text{Moles of salicylic acid}=\frac{100g}{138.121g/mol}=0.724mol

For the given chemical reaction:

C_7H_6O_3+C_4H_6O_3\rightarrow C_9H_8O_4+CH_3COOH

By stoichiometry of the reaction:

1 mole of salicylic acid reacts with 1 mole of acetic anhydride.

So, 0.724 moles of salicylic acid will react with = \frac{1}{1}\times 0.724=0.724mol of acetic anhydride.

Now, to calculate the mass of acetic anhydride, we use equation 1:

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Putting values in equation 1, we get:

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Hence, the mass of acetic anhydride needed is 73.91 grams.

  • <u>For b:</u>

By stoichiometry of the reaction:

1 mole of salicylic acid is producing 1 mole of aspirin.

So, 0.724 moles of salicylic acid will produce = \frac{1}{1}\times 0.724=0.724mol of aspirin.

Now, to calculate the mass of aspirin, we use equation 1:

Moles of aspirin = 0.724 moles

Molar mass of aspirin = 180.158 g/mol

Putting values in equation 1, we get:

0.724mol=\frac{\text{Mass of aspirin}}{180.158g/mol}\\\\\text{Mass of aspirin}=130.43g

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