Answer: Structural Isomers
Explanation:
The compounds having similar molecular formula but different arrangement of atoms or groups in space are called isomers and the phenomenon is called as isomerism.
Isomers are of two types: structural isomers and stereo isomers.
Structural isomers are isomers in which molecules with the same molecular formula have different bonding patterns.
Stereoisomers are isomers in which molecules have the same molecular formula and sequence of bonded atoms but differ in the three-dimensional orientations of their atoms in space.
Thus when molecules have the same number of each element but those atoms are arranged differently they are known as Structural isomers.
Elements with three p-electrons....
That would be N, P, As, Sb, and Bi -- elements in group 15
For example, energy diagram showing "empty" orbitals up through the 3p.
.....3p __ __ __
3s __
.....2p __ __ __
2s __
1s __
Energy diagram of phosphorous showing three unpaired electrons in 3p-sublevel
.....3p ↑_ ↑_ ↑_
3s ↑↓
.....2p ↑↓ ↑↓ ↑↓
2s ↑↓
1s ↑↓
According to Hund's rule, the electrons singly occupy the p-orbitals, and all have the same spin.
The chemical equation would be:
2NO(g) + O2(g) --> 2NO2 (g)
<span>At equilibrium state, the partial pressure of the gases would be as follows : </span>
<span>NO = 522 - 2x </span>
<span>O2 = 421 - x </span>
<span>NO2 = 2x </span>
<span>- - - - - - - - - - - - -</span>
<span>943 - x = 748 </span>
<span>x = 195</span>
Calculating for Kp,
<span>Kp = (NO2)^2/ ((NO)^2 * (O2)) </span>
<span>Kp = (2 * 195)^2/ ((522 - 2 * 195)^2 * (421 - 195)) </span>
<span>Kp = 0.0386 </span>
