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Svetradugi [14.3K]
3 years ago
11

Water's heat of fusion is 80. cal/g , its specific heat is 1.0calg⋅∘C, and its heat of vaporization is 540 cal/g . A canister is

filled with 320 g of ice and 100. g of liquid water, both at 0 ∘C . The canister is placed in an oven until all the H2O has boiled off and the canister is empty. How much energy in calories was absorbed?
Chemistry
1 answer:
Pani-rosa [81]3 years ago
6 0
<span>294400 cal The heating of the water will have 3 phases 1. Melting of the ice, the temperature will remain constant at 0 degrees C 2. Heating of water to boiling, the temperature will rise 3. Boiling of water, temperature will remain constant at 100 degrees C So, let's see how many cal are needed for each phase. We start with 320 g of ice and 100 g of liquid, both at 0 degrees C. We can ignore the liquid and focus on the ice only. To convert from the solid to the liquid, we need to add the heat of fusion for each gram. So multiply the amount of ice we have by the heat of fusion. 80 cal/g * 320 g = 25600 cal Now we have 320 g of ice that's been melted into water and the 100 g of water we started with, resulting in 320 + 100 = 420 g of water at 0 degrees C. We need to heat that water to 100 degrees C 420 * 100 = 42000 cal Finally, we have 420 g of water at the boiling point. We now need to pump in an additional 540 cal/g to boil it all away. 420 g * 540 cal/g = 226800 cal So the total number of cal used is 25600 cal + 42000 cal + 226800 cal = 294400 cal</span>
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[Cl₂] in equilibrium is 1.26 M

Explanation:

This is the equilibrium:

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So let's analyse, all the process:

                PCl₃(g)        +        Cl₂(g)     ⇋        PCl₅(g)

Initially     0.24 M                 1.50M                 0.12 M

React           x                           x                         x

Some amount of compound has reacted during the process.

In equilibrium we have

              0.24 - x                  1.50 - x                  0.12 + x

As initially we have moles of product, in equilibrium we have to sum them.

Let's make the expression for Kc

Kc = [PCl₅] / [Cl₂] . [PCl₃]

91 = (0.12 + x) / (0.24 - x) ( 1.50 - x)

91 = (0.12 + x) / (0.36 - 0.24x - 1.5x + x²)          

91 (0.36 - 0.24x - 1.5x + x²) = (0.12 + x)

32.76 - 158.34x + 91x² = 0.12 +x

32.64 - 159.34x + 91x² = 0

This a quadratic function:

a = 91; b= -159.34; c = 32.64

(-b +- √(b² - 4ac)) / 2a

Solution 1 = 1.5

Solution 2 = 0.23 (This is our value)

So [Cl₂] in equilibrium is 1.50 - 0.23 = 1.26 M

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