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Firlakuza [10]
4 years ago
7

2. For the reaction, 2SO2(g) + O2(g) 2SO3(g), at 450.0 K the equilibrium con¬stant, Kc, has a value of 4.62. A system was charge

d to give these initial concentrations, [SO3] = 0.254 M, [O2] = 0.00855 M, [SO2] = 0.500 M. In which direction will it go?
Chemistry
2 answers:
miv72 [106K]4 years ago
6 0

Answer:

Q >> Kc

We have more products than reactans. To reach the equilibrium, the balance will shift to the left.

Explanation:

Step 1: Data given

Temperature = 450.0 K

Kc = 4.62

When Kc > Q, we have more reactants than products. To reach the equilibrium, the balance will shift to the right

When Kc < Q, we have more products than reactans. To reach the equilibrium, the balance will shift to the left.

When Kc = Q,the equiation isatequilibrium

[SO3] = 0.254 M

[O2] = 0.00855 M

[SO2] = 0.500 M

Step 2: The balanced equation

2SO2(g) + O2(g) ⇄ 2SO3(g)

Step 3: Calculate the Q

Q = [SO3]² / [O2][SO2]²

Q = 0.254²/ (0.500 * 0.00855²)

Q = 1765

Q >> Kc

We have more products than reactans. To reach the equilibrium, the balance will shift to the left.

vagabundo [1.1K]4 years ago
6 0

Answer:

the reaction will favor forward, the products.

Explanation:

reaction:

  • 2SO2(g) + O2(g) → 2SO3(g)

∴ Kc = 4.62 = [SO3]² / ([O2]*[SO2]²)

initial concentration:

∴ [SO3]i = 0.254 M

∴ [O2]i = 0.00855 M

∴ [SO2]i = 0.500 M

reaction quotient (Q):

⇒ Q = [SO3]² / ([O2]*[SO2]²)

⇒ Q = (0.254)² / ((0.0085)(0.500)²)

⇒ Q = 30.3605

using the reaction quotient to predict the direction of the reaction:

⇒ Q < Kc

In this case, the ratio of products to reagents is less than for the equilibrium system. In other words, the concentration of the reagents is higher than it would be at equilibrium.

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<h3>Explanation</h3>

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which is equivalent to

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The question states that the second equation has an enthalpy, or "heat", of neutralization of -56.2 \; \text{kJ}. Thus the combination of every mole of hydrogen ions and hydroxide ions in solution would produce 56.2 \; \text{kJ} or 56.2 \times 10^{3}\; \text{J} of energy.

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Both the solution and the calorimeter absorb energy released in this neutralization reaction. Their temperature change is dependent on the heat capacity <em>C</em> of the two objects, combined.

The question has given the heat capacity of the calorimeter directly.

The heat capacity (the one without mass in the unit) of water is to be calculated from its mass and <em>specific</em> heat.

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