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valkas [14]
3 years ago
14

Why is a cis-1,3-disubstituted cyclohexane more stable thanits trans isomer?

Chemistry
1 answer:
anzhelika [568]3 years ago
5 0

Answer:

Explanation has been given below

Explanation:

  • In diaxial conformation of cis-1,3-disubstituted cyclohexane, 4 gauche-butane interactions along with syn-diaxial interaction are present. Hence it readily gets converted to diequitorial conformation where no such gauche-butane interaction is present
  • In two possible conformations of trans-1,3-disubstituted cyclohexane, 2 gauche-butane interactions are present in each of them.
  • Hence cis-1,3-disubstituted cyclohexane exists almost exclusively in diequitorial form. But trans-1,3-disubstituted cyclohexane has no such option.
  • Trans-1,3-disubstituted cyclohexane experiences gauche butane interaction in each of the two conformations.
  • Therefore cis-1,3-disubstituted cyclohexane is more stable than trans conformation

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An oxide of nitrogen contains 30.45 mass % N.
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An oxide of nitrogen contains 30.45 mass % N, if the molar mass is 90± 5 g/mol the molecular formula is N₂O₄.

<h3>What is molar mass?</h3>

The molar mass of a chemical compound is determined by dividing its mass by the quantity of that compound, expressed as the number of moles in the sample, measured in moles. A substance's molar mass is one of its properties. The compound's molar mass is an average over numerous samples, which frequently have different masses because of isotopes.

<h3>How to find the molecular formula?</h3>

The whole-number multiple is defined as follows.

Whole-number multiple = \frac{molar mass (g/mol)}{empirical formula mass (g/mol)}

The empirical formula mass is shown below.

Mw of empirical formula = Mw of N+ 2 x (Mw of O)

                                      = 14.01 g/mol + 2 x (16.00 g/mol)

                                      = 46.01 g/mol

With the given molar mass or the molecular formula mass, we can get the whole-number multiple for the compound.

Whole-number multiple = \frac{90 g/mol }{46.01 g/mol} ≈ 2

Multiplying the subscripts of NO2 by 2, the molecular formula is N(1x2)O(2x2)= N2O4.

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2 years ago
The representative particle for KBr is the?​
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Answer:

This is a chemical symbol for Potassium Bromide

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3 years ago
Question 3:
Oliga [24]
E. Molarity of vinegar

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3 years ago
Calculate the number of grams of sodium chloride in the solution. (Hint: Remember that sodium chloride is a strong electrolyte.)
creativ13 [48]

The question is incomplete, here is the complete question:

A solution contains 0.115 mol  H_2O and an unknown number of moles of sodium chloride. The vapor pressure of the solution at  30°C  is 25.7 torr. The vapor pressure of pure water at this temperature is 31.8 torr. Calculate the number of grams of sodium chloride in the solution. (Hint: Remember that sodium chloride is a strong electrolyte.)

<u>Answer:</u> The mass of sodium chloride in the solution is 0.714 grams

<u>Explanation:</u>

The formula for relative lowering of vapor pressure will be:

\frac{p^o-p_s}{p^o}=i\times \chi_{\text{solute}}

where,  

p^o = vapor pressure of solvent (water) = 31.8 torr

p^s = vapor pressure of the solution = 25.7 torr

i = Van't Hoff factor = 2

\chi_{\text{solute}} = mole fraction of solute (sodium chloride) = ?

Putting values in above equation, we get:

\frac{31.8-25.7}{31.8}=2\times \chi_{NaCl}\\\\\chi_{NaCl}=0.0959

Mole fraction of a substance is calculated by using the equation:

\chi_A=\frac{n_A}{n_A+n_B}

\chi_{\text{NaCl}}=\frac{n_{\text{NaCl}}}{n_{\text{NaCl}}+n_{\text{water}}}

We are given:

Moles of water = 0.115 moles

0.0959=\frac{n_{\text{NaCl}}}{n_{\text{NaCl}}+0.115}\\\\n_{\text{NaCl}}=0.0122mol

To calculate the mass for given number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}

Moles of NaCl = 0.0122 moles

Molar mass of NaCl = 58.5 g/mol

Putting values in above equation, we get:

0.0122mol=\frac{\text{Mass of NaCl}}{58.5g/mol}\\\\\text{Mass of NaCl}(0.0122mol\times 58.5g/mol)=0.714g

Hence, the mass of sodium chloride in the solution is 0.714 grams

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3 years ago
Dana is trying to determine if an unknown sample is a pure substance or not. The sample has a cloudy white color, and it seems e
Firdavs [7]

Answer:

Dana filtered the sample and larger granules of the sample were left behind.

Explanation:

If a substance is pure, it will have a uniform composition throughout. It will not separate into particles of various sizes.

One of the characteristics of pure substances is that they are homogeneous. A mixture is definitely made up of particles of various sizes.

Since the particles was filtered and larger granules were left behind, the sample has been separated by a physical method (filtration). Only a mixture can be separated by physical methods. It is not a pure substance.

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