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Alex787 [66]
3 years ago
12

Pure chlorobenzene (C6H5Cl) has a normal boiling point of 131.00 °C. A solution of 32.5 g of 2,8-dibromodibenzofuran (C12H6Br2O)

in 195 g of chlorobenzene has a boiling point of 133.30 °C. Calculate Kbp for chlorobenzene based on this experiment.
Chemistry
1 answer:
vichka [17]3 years ago
3 0

Answer:

Kb →  1.56 °C / m

Explanation:

This is all about boiling point elevation, the colligative property that shows that boiling point for a solution is higher than boiling point of pure solvent.

This is the formula: ΔT = Kb . m . i

where i is the Van't Hoff factor (ions dissolved in solution). As these are organic compounds, we assume they are non electrolytic,

m is molality (mol of solute / 1kg of solvent)

Kb is our unknown. The value for ebulloscopic constant, it is specific for each solvent.

ΔT = T° boiling from solution - T° boiling from solute

First of all, let's determine the moles of solute.

Mass / Molar mass → 32.5 g/ 113.45 g/mol = 0.286 mol

Molality is mol of solute/ 1 kg of solvent

We must convert the mass from g to kg

195g . 1kg /1000 = 0.195 kg

Molality = 0.286 mol / 0.195 kg = 1.47 m

Let's replace the values in the formula

133.30 °C - 131°C = Kb . 1.47m .1

2.30°C / 1.47 m =  Kb →  1.56 °C / m

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Based on the given information, the volume of KOH given is 19.55 ml, the volume of sulfuric acid given is 20.20 ml, and the molarity of sulfuric acid is 0.3467 M. There is a need to find the molarity of KOH.

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