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Alex787 [66]
3 years ago
12

Pure chlorobenzene (C6H5Cl) has a normal boiling point of 131.00 °C. A solution of 32.5 g of 2,8-dibromodibenzofuran (C12H6Br2O)

in 195 g of chlorobenzene has a boiling point of 133.30 °C. Calculate Kbp for chlorobenzene based on this experiment.
Chemistry
1 answer:
vichka [17]3 years ago
3 0

Answer:

Kb →  1.56 °C / m

Explanation:

This is all about boiling point elevation, the colligative property that shows that boiling point for a solution is higher than boiling point of pure solvent.

This is the formula: ΔT = Kb . m . i

where i is the Van't Hoff factor (ions dissolved in solution). As these are organic compounds, we assume they are non electrolytic,

m is molality (mol of solute / 1kg of solvent)

Kb is our unknown. The value for ebulloscopic constant, it is specific for each solvent.

ΔT = T° boiling from solution - T° boiling from solute

First of all, let's determine the moles of solute.

Mass / Molar mass → 32.5 g/ 113.45 g/mol = 0.286 mol

Molality is mol of solute/ 1 kg of solvent

We must convert the mass from g to kg

195g . 1kg /1000 = 0.195 kg

Molality = 0.286 mol / 0.195 kg = 1.47 m

Let's replace the values in the formula

133.30 °C - 131°C = Kb . 1.47m .1

2.30°C / 1.47 m =  Kb →  1.56 °C / m

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Answer:

Approximately 1.95 \times 10^{2}\; \rm J.

Explanation:

Look up the specific heat of gaseous neon:

c = 1.03 \; \rm J \cdot g^{-1} \cdot K^{-1}.

Calculate the required temperature change:

\Delta T = (37.9 - 20.0)\; \rm K = 17.9\; \rm K.

Let m denote the mass of a sample of specific heat C. Energy required to raise the temperature of this sample by \Delta T:

Q = c \cdot m \cdot \Delta T.

For the neon gas in this question:

  • c = 1.03\; \rm J \cdot g^{-1}\cdot K^{-1}.
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  • \Delta T = (37.9 - 20.0)\; \rm K = 17.9\; \rm K.

Calculate the energy associated with this temperature change:

\begin{aligned}Q &= c \cdot m \cdot \Delta T \\ &= 1.03\; \rm J \cdot g^{-1}\cdot K^{-1} \times 10.6\; \rm g \times 17.9\; \rm K \\ &\approx 1.95 \times 10^{2}\; \rm J\end{aligned}.

3 0
3 years ago
If you have 5.42 x 1024 aluminum atoms, approximately how many moles is that
sattari [20]

Answer:

<h2>9.00 moles</h2>

Explanation:

To find the number of moles in a substance given it's number of entities we use the formula

n =  \frac{N}{L} \\

where n is the number of moles

N is the number of entities

L is the Avogadro's constant which is

6.02 × 10²³ entities

From the question we have

n =  \frac{5.42 \times  {10}^{24} }{6.02 \times {10}^{23} }  \\  = 9.0033

We have the final answer as

<h3>9.00 moles</h3>

Hope this helps you

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