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Alex787 [66]
3 years ago
12

Pure chlorobenzene (C6H5Cl) has a normal boiling point of 131.00 °C. A solution of 32.5 g of 2,8-dibromodibenzofuran (C12H6Br2O)

in 195 g of chlorobenzene has a boiling point of 133.30 °C. Calculate Kbp for chlorobenzene based on this experiment.
Chemistry
1 answer:
vichka [17]3 years ago
3 0

Answer:

Kb →  1.56 °C / m

Explanation:

This is all about boiling point elevation, the colligative property that shows that boiling point for a solution is higher than boiling point of pure solvent.

This is the formula: ΔT = Kb . m . i

where i is the Van't Hoff factor (ions dissolved in solution). As these are organic compounds, we assume they are non electrolytic,

m is molality (mol of solute / 1kg of solvent)

Kb is our unknown. The value for ebulloscopic constant, it is specific for each solvent.

ΔT = T° boiling from solution - T° boiling from solute

First of all, let's determine the moles of solute.

Mass / Molar mass → 32.5 g/ 113.45 g/mol = 0.286 mol

Molality is mol of solute/ 1 kg of solvent

We must convert the mass from g to kg

195g . 1kg /1000 = 0.195 kg

Molality = 0.286 mol / 0.195 kg = 1.47 m

Let's replace the values in the formula

133.30 °C - 131°C = Kb . 1.47m .1

2.30°C / 1.47 m =  Kb →  1.56 °C / m

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A first-order reaction has a half-life of 29.2 s . how long does it take for the concentration of the reactant in the reaction t
Dmitriy789 [7]

Answer is: it takes 116,8 seconds to fall to one-sixteenth of its initial value

<span> The half-life for the chemical reaction is 29,2 s and is independent of initial concentration.
c</span>₀ - initial concentration the reactant.

c - concentration of the reactant remaining at time.

t = 29,2 s.<span>
First calculate the rate constant k:
k = 0,693 ÷ t = 0,693 ÷ 29,2 s</span> = 0,0237 1/s.<span>
ln(c/c</span>₀) = -k·t₁.<span>
ln(1/16 </span>÷ 1) = -0,0237 1/s · t₁.

t₁ = 116,8 s.

5 0
3 years ago
Which buffer would be better able to hold a steady pH on the addition of strong acid, buffer 1 or buffer 2? Explain. Buffer 1: a
Talja [164]

Answer:

Buffer 1.

Explanation:

Ammonia is a weak base. It acts like a Bronsted-Lowry Base when it reacts with hydrogen ions.

\rm NH_3\; (aq) + H^{+}\; (aq) \to {NH_4}^{+}\; (aq).

\rm NH_3 gains one hydrogen ion to produce the ammonium ion \rm {NH_4}^{+}. In other words, \rm {NH_4}^{+} is the conjugate acid of the weak base \rm NH_3.

Both buffer 1 and 2 include

  • the weak base ammonia \rm NH_3, and
  • the conjugate acid of the weak base \rm {NH_4}^{+}.

The ammonia \rm NH_3 in the solution will react with hydrogen ions as they are added to the solution:

\rm NH_3\; (aq) + H^{+}\; (aq) \to {NH_4}^{+}\; (aq).

There are more \rm NH_3 in the buffer 1 than in buffer 2. It will take more strong acid to react with the majority of \rm NH_3 in the solution. Conversely, the pH of buffer 1 will be more steady than that in buffer 2 when the same amount of acid has been added.

5 0
3 years ago
Need help
KengaRu [80]

Answer:

The answers are either 1 or 4

Explanation:

I am pretty dure it is 1

3 0
2 years ago
A solution was prepared by mixing 20.00 mL of 0.100 M and 120.00 mL of 0.200 M. Calculate the molarity of the final solution of
Marat540 [252]

Answer:

0.186M

Explanation:

First, we need to obtain the moles of nitric acid that are given for each solution. Then, we need to divide these moles in total volume (120mL + 20mL = 140mL = 0.140L) to obtain molarity:

<em>Moles Nitric acid:</em>

0.0200L * (0.100mol / L) = 0.00200 moles

0.120L * (0.200mol / L)= 0.02400 moles

Total moles: 0.02400moles + 0.00200moles = 0.026 moles of nitric acid

Molarity: 0.026 moles / 0.140L

<h3>0.186M</h3>
6 0
3 years ago
A machine shop worker records the mass of an aluminum cube as 176 g. If one side of the cube measures 4 cm, what is the density
forsale [732]

Answer:

Explanation:

So we take the given quotient:

ρ=176⋅g4⋅cm×4⋅cm×4⋅cm = 176⋅g64⋅cm3 = ??g⋅cm−3.

Would the cube float or sink in water? Why

6 0
3 years ago
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