Pyridine reacts with hydroxide by nucleophilic aromatic substitution. complete the mechanism by drawing curved arrows, the struc
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Answer:
a) for adiabatic reversible, ΔU(internal energy is constant) = 0, ΔH = 0(no heat is entering or leaving the surrounding)
workdone (w) = -8442.6 J ≈ -8.443 KJ
heat transferred (q) of the ideal gas = - w
q = 8.443 KJ
b) For ideal gas at adiabatic reversible, Internal energy (ΔU) = 0 and enthalpy (ΔH) = 0
the workdone(w) in the ideal gas= - 4567.5 J ≈ - 4.57 KJ
the heat transfer (q) of an ideal gas = 4.5675 KJ
Explanation:
given
mole of an ideal gas(n) = 2.5 mol
Temperature (T) = 20°C
= (20°C + 273) K = 293 K
Initial pressure of the ideal gas(P₁) = 20 atm
Final pressure of the ideal gas(P₂) = 5 atm.
2) (a)for adiabatic reversible process,
note: adiabatic process is a process by which no heat or mass is transferred between the system and its surrounding.
Work done (w) = nRT ln
= 2.5 mol × 8.314 J/mol K × 293 K × ln
= 6090.01 J × [-1.3863]
= -8442.6 J ≈ -8.443 KJ
So, the work done (w) of ideal gas = -8.443 KJ
For ideal gas at adiabatic reversible, Internal energy (U) = 0 and Enthalpy (H) = 0
From first law of thermodynamics:-
U = q + w
0 = q + w
q = - w
q = - (-8.443 KJ)
q = 8.443 KJ
heat transfer (q) of the ideal gas = 8.443 KJ
(b) For adiabatic irreversible, the temperature T remains constant because the internal energy U depends only on temperature T. Since at constant temperature, the entropy is proportional to the volume, therefore, entropy will increase.
Work done (w) = -nRT(1 - ln
)
= - 2.5 mol × 8.314 J / mol K× 293 K × [1- (5 atm /20 atm)]
= - 6090.01 J × 0.75
= - 4567.5 J ≈ - 4.57 KJ
∴work done(w) of an ideal gas = - 4.57 KJ
For ideal gas at adiabatic Irreversible, Internal energy (U) = 0 and Enthalpy (H) = 0
From first law of thermodynamics:-
U = q + w
0 = q + w
q = - w
q = - (-4.5675 KJ)
q = 4.5675 KJ
the heat transfer (q) of an ideal gas = 4.5675 KJ
Answer:
a) IUPAC Names:
1) (<em>trans</em>)-but-2-ene
2) (<em>cis</em>)-but-2-ene
3) but-1-ene
b) Balance Equation:
C₄H₁₀O + H₃PO₄ → C₄H₈ + H₂O + H₃PO₄
As H₃PO₄ is catalyst and remains unchanged so we can also write as,
C₄H₁₀O → C₄H₈ + H₂O
c) Rule:
When more than one alkene products are possible then the one thermodynamically stable is favored. Thermodynamically more substituted alkenes are stable. Furthermore, trans alkenes are more stable than cis alkenes. Hence, in our case the major product is trans alkene followed by cis. The minor alkene is the 1-butene as it is less substituted.
d) C is not Geometrical Isomer:
For any alkene to demonstrate geometrical isomerism it is important that there must be two different geminal substituents attached to both carbon atoms. In 1-butene one carbon has same geminal substituents (i.e H atoms). Hence, it can not give geometrical isomers.
