Answer:
0.2 mL stock solution, 0.8 solvent, 0.1 mL first solution and 0.9 solvent
Explanation:
The final volume for fist solution is 1 mL and concentration must will be 1/5, then 1 mL/5=0.2 mL. For complete the 1 mL add the missing solvent volume 1 mL-0.2 mL=0.8 mL. For second solution, assuming final volume is 1 mL, and concentration 1/10, then we have 1 mL /10=0.1 mL solution 1/5. Completing volume, 1 mL-0.1 mL= 0.9 mL solvent.
Answer:
Explanation:
<u>1) Rate law, at a given temperature:</u>
- Since all the data are obtained at the same temperature, the equilibrium constant is the same.
- Since only reactants A and B participate in the reaction, you assume that the form of the rate law is:
r = K [A]ᵃ [B]ᵇ
<u>2) Use the data from the table</u>
- Since the first and second set of data have the same concentration of the reactant A, you can use them to find the exponent b:
r₁ = (1.50)ᵃ (1.50)ᵇ = 2.50 × 10⁻¹ M/s
r₂ = (1.50)ᵃ (2.50)ᵇ = 2.50 × 10⁻¹ M/s
Divide r₂ by r₁: [ 2.50 / 1.50] ᵇ = 1 ⇒ b = 0
- Use the first and second set of data to find the exponent a:
r₁ = (1.50)ᵃ (1.50)ᵇ = 2.50 × 10⁻¹ M/s
r₃ = (3.00)ᵃ (1.50)ᵇ = 5.00 × 10⁻¹ M/s
Divide r₃ by r₂: [3.00 / 1.50]ᵃ = [5.00 / 2.50]
2ᵃ = 2 ⇒ a = 1
<u>3) Write the rate law</u>
This means, that the rate is independent of reactant B and is of first order respect reactant A.
<u>4) Use any set of data to find K</u>
With the first set of data
- r = K (1.50 M) = 2.50 × 10⁻¹ M/s ⇒ K = 0.250 M/s / 1.50 M = 0.167 s⁻¹
Result: the rate constant is K = 0.167 s⁻¹
1.0×10^−15/4.2×10^−7=<span>2.3809524e-23 Hoped I helped!</span>
Answer:
a. The reaction associated with DHºf for an ionic compound
Explanation:
An exothermic process is a process that loses heat for the surroundings, so the temperature of the system must decrease, and ΔH must be negative.
DHºf or ΔHºf of an ionic compound is always negative because the final energy is always lower than the initial. It happens because of the stability of the bond, the system wants a lower energy state to be stable.
The ionization of a lithium atom occurs with the gain of energy, which is given to the electron, so it may give off the atom. So it's an endothermic process.
To change the state of a solid to a gas (sublimation), the compound must gain heat, its temperature must increase, so it's always an endothermic process.
To break a covalent bond it's necessary the gain of energy, so it's an endothermic process.
