The number 6.022 × 1023 indicating the number of atoms or molecules in a mole of any substance
Answer:
Less
Explanation:
Since [Cu(NH3)4]2+ and [Cu(H2O)6]2+ are Octahedral Complexes the transitions between d-levels explain the majority of the absorbances seen in those chemical compounds. The difference in energy between d-levels is known as ΔOh (ligand-field splitting parameter) and it depends on several factors:
- The nature of the ligand: A spectrochemical series is a list of ligands ordered on ligand strength. With a higher strength the ΔOh will be higher and thus it requires a higher energy light to make the transition.
- The oxidation state of the metal: Higher oxidation states will strength the ΔOh because of the higher electrostatic attraction between the metal and the ligand
A partial spectrochemical series listing of ligands from small Δ to large Δ:
I− < Br− < S2− < Cl− < N3− < F−< NCO− < OH− < C2O42− < H2O < CH3CN < NH3 < NO2− < PPh3 < CN− < CO
Then NH3 makes the ΔOh higher and it requires a higher energy light to make the transition, which means a shorter wavelength.
Answer:
22.73s
Explanation:
The reaction is a second order reaction, we know this by observing the unit of the slope.
rate constant = k = 0.056 M-1s-1
the initial concentration of BrO- [A]o = 0.80 M
time = ?
Final concentration [A]t= one-half of 0.80 M = 0.40M
1 / [A]t = kt + 1 / [A]o
1 / 0.40 = 0.056 * t + 1 / 0.80
t = (2.5 - 1.25) / 0.056
t = 22.73s
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