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Marat540 [252]
3 years ago
10

How many ml of 0.01-m naoh will be required to titrate 0.061-g of khp to it's endpoint?

Chemistry
1 answer:
hjlf3 years ago
6 0
The volume of NaOH needed for the titration is calculated by equating the number of moles of KHP and NAOH.

(1) number of moles of KHP:
         n = mass of KHP / molar mass of KHP
Substituting,
         n = 0.061 g / (204.22 g/mol) = 2.987 x 10⁻⁴ moles KHP

(2) number of moles of NaOH
         n = (volume NaOH in L)(molarity of NaOH)
          n = V x 0.01

Equating,
       0.01V = 2.987 x 10⁻⁴

The value of V from the equation is 0.0299L of NaOH. 

Converting the value to mL will give us the answer of 29.87 mL. 
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Does it take more, less, or the same amount of heat to melt 1.0 kg of ice at 0°C, or to bring 1.0 kg of liquid water at 0°C to t
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Answer : It takes less amount of heat to metal 1.0 Kg of ice.

Solution :

The process involved in this problem are :

(1):H_2O(s)(0^oC)\rightarrow H_2O(l)(0^oC)\\\\(2):H_2O(l)(0^oC)\rightarrow H_2O(l)(100^oC)

Now we have to calculate the amount of heat released or absorbed in both processes.

<u>For process 1 :</u>

Q_1=m\times \Delta H_{fusion}

where,

Q_1 = amount of heat absorbed = ?

m = mass of water or ice = 1.0 Kg

\Delta H_{fusion} = enthalpy change for fusion = 3.35\times 10^5J/Kg

Now put all the given values in Q_1, we get:

Q_1=1.0Kg\times 3.35\times 10^5J/Kg=3.35\times 10^5J

<u>For process 2 :</u>

Q_2=m\times c_{p,l}\times (T_{final}-T_{initial})

where,

Q_2 = amount of heat absorbed = ?

m = mass of water = 1.0 Kg

c_{p,l} = specific heat of liquid water = 4186J/Kg^oC

T_1 = initial temperature = 0^oC

T_2 = final temperature = 100^oC

Now put all the given values in Q_2, we get:

Q_2=1.0Kg\times 4186J/Kg^oC\times (100-0)^oC

Q_2=4.186\times 10^5J

From this we conclude that, Q_1 that means it takes less amount of heat to metal 1.0 Kg of ice.

Hence, the it takes less amount of heat to metal 1.0 Kg of ice.

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3 years ago
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