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Reduction reactions are those reactions that reduce the oxidation number of a substance. Hence, the product side of the reaction must contain excess electrons. The opposite is true for oxidation reactions. When you want to determine the potential difference expressed in volts between the cathode and anode, the equation would be: E,reduction - E,oxidation.
To cancel out the electrons, the e- in the reactions must be in opposite sides. To do this, you reverse the equation with the negative E0, then replacing it with the opposite sign.
Pb(s) --> Pb2+ +2e- E0 = +0.13 V
Ag+ + e- ---> Ag E0 = +0.80 V
Adding up the E0's would yield an overall electric cell potential of +0.93 V.
Answer:
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Oxidation state of I is (-1) and for CO it is zero. Let's assume that the oxidation state of Fe in Fe(CO)₄I₂<span> (s) is x. For whole compound, the charge is zero.
Sum of oxidation numbers in all elements = Charge of the compound.
Here we have 1Fe , 4CO and 2I
hence we can find the oxidation state as;
x + 4*0 + 2*(-1) = 0
x + 0 - 2 = 0
x = +2
Hence the oxidation state of Fe in product </span>Fe(CO)₄I₂ (s) is +2.
Same as we can find the oxidation state (y) of Fe in Fe(CO)₅(s).
y + 5*0 = 0
y = 0
Since oxidation state of Fe increased from 0 to +2, the oxidized element is Fe in the given reaction.