<u>Answer:</u> The mass of iron (III) chloride that must be added is 81.1 grams
<u>Explanation:</u>
To calculate the number of moles, we use the equation:
.....(1)
Given mass of NaOH = 60 g
Molar mass of NaOH = 40 g/mol
Putting values in equation 1, we get:

The chemical equation for the reaction of iron (III) chloride and NaOH follows:

By Stoichiometry of the reaction:
3 moles of NaOH reacts with 1 mole of iron (III) chloride
So, 1.5 moles of NaOH will react with =
of iron (III) chloride
Now, calculating the mass of iron (III) chloride from equation 1, we get:
Molar mass of iron (III) chloride = 162.2 g/mol
Moles of iron (III) chloride = 0.5 moles
Putting values in equation 1, we get:

Hence, the mass of iron (III) chloride that must be added is 81.1 grams