Q: What is the change of entropy for 3.0 kg of water when the 3.0 kg of water is changed to ice at 0 °C? (Lf = 3.34 x 105 J/kg)
Answer:
-3670.33 J/K
Explanation:
Entropy: This can be defined as the degree of randomness or disorderliness of a substance. The S.I unit of Entropy is J/K.
Mathematically, change of Entropy can be expressed as,
ΔS = ΔH/T ....................................... Equation 1
Where ΔS = Change of entropy, ΔH = heat change, T = temperature.
ΔH = -(Lf×m).................................... Equation 2
Note: ΔH is negative because heat is lost.
Where Lf = latent heat of ice = 3.34×10⁵ J/kg, m = 3.0 kg, m = mass of water = 3.0 kg
Substitute into equation
ΔH = -(3.34×10⁵×3.0)
ΔH = - 1002000 J.
But T = 0 °C = (0+273) K = 273 K.
Substitute into equation 1
ΔS = -1002000/273
ΔS = -3670.33 J/K
Note: The negative value of ΔS shows that the entropy of water decreases when it is changed to ice at 0 °C
Answer:
Chromium
Explanation:
Cr has 24 atomic number and mass number 52
Answer:
130ml of HCl(36%) in 4.90L solution => pH = 1.50
Explanation:
Need 4.90L of HCl(aq) solution with pH = 1.5.
Given pH = 1.5 => [H⁺] = 10⁻¹·⁵M = 0.032M in H⁺
[HCl(36%)] ≅ 12M in HCl
(M·V)concentrate = (M·V)diluted
12M·V(conc) = 0.032M·4.91L
=> V(conc) needed = [(0.032)(4.91)/12]Liters = 0.0130Liters or 130 ml.
Mixing Caution => Add 131 ml of HCl(36%) into a small quantity of water (~500ml) then dilute to the mark.
Explanation:
Given -
- An organic compound gives H₂ gas with Na
- On treatment with alkaline iodine it gives yellow ppt.
- On oxidation with CrO₃/H⁺ forms an aldehyde (C₂H₄O)
To Find -
- Name the compound and write the reaction involved
Now,
Let A be the organic compound.
Then,
- A + Na → + H₂↑
- A + I₂ → CHI₃ (yellow ppt.)
- A + CrO₃ + H⁺ → C₂H₄O
Now,
Here we see that compound A reacts with chromic oxide (CrO₃) in the presence of acidic medium gives aldehyde.
- Functional group of aldehyde = —CHO
And It forms only 2 Carbon aldehyde it means, It is Ethanal (CH₃CHO).
Compound A reacts with chromic oxide (CrO₃) in the presence of acidic medium gives ethanal.
It means,
We know that 1° alcohol on oxidation gives aldehyde.
Here it gives 2 Carbon aldehyde.
It means,
Here 2 Carbon and 1° alcohol is used.
Now,
Its cleared that Compound A is Ethanol.
Reaction Involved -
- CH₃CH₂OH + Na → CH₃CH₂O⁻Na⁺ + H₂↑
- CH₃CH₂OH + I₂ + OH⁻ → CHI₃↓ + HCOO⁻ + HI + H₂O
- CH₃CH₂OH + CrO₃ + H⁺ → CH₃CHO
Distillation :)
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