The question is incomplete. Complete question is attached below
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Correct Answer:
Option C i.e. I ~ III < IV < V < II
Reason:
During a nucleophilic subsitution reaction of chloroarenes, Cl- group is replaced by an nucleophile like OH-.
Order of reactivity, during such reactions depends on the electron density on carbon atom that is attached to Cl. Lower the electron density, greater will be the reactivity.Among the provided chloroarenes, electron density on C atom will be minimum in case of compound II, because of presence of electron withdrawing group (-NO2) at ortho and para position. Due to this, there will be large number of resonating structures. This signifies greater electron de-localization, and hence largest reactivity for nucleophilic substitution reaction.
Followed by this, compound V will show greater reactivity, due to presence of -NO2 group at para and one of the ortho position. Compound IV will have less number of resonating structures as compared to compound II and V, hence it will display poor reactivity towards nucleophilic substitution reaction.
Finally, compound 1 and III will minimum reactivity towards nucleophilic substitution reaction, because -NO2 group present at meta position (compound III) will not participate in resonance.
Answer: Option (c) is the correct answer.
Explanation:
Activation energy or free energy of a transition state is defined as the minimum amount of energy required to by reactant molecules to undergo a chemical reaction.
So, when activation energy is decreased then molecules with lesser amount of energy can also participate in the reaction. This leads to an increase in rate of reaction.
Also, increase in temperature will help in increasing the rate of reaction.
Whereas at a given temperature, every molecule will have different energy because every molecule travels at different speed.
Hence, we can conclude that out of the given options false statement is that at a given temperature and time all molecules in a solution or a sample will have the same energy.
Answer:
The enthalpy of the reaction is –184.6 kJ, and the reaction is exothermic.
Explanation:
Answer: It will take 8.2 minutes until the concentration decreases to 0.055 M
Explanation:
The time after which 99.9% reactions gets completed is 40 minutes
Explanation:
Expression for rate law for first order kinetics is given by:

where,
k = rate constant
t = age of sample
a = let initial amount of the reactant
a - x = amount left after decay process
a) for completion of half life:
Half life is the amount of time taken by a radioactive material to decay to half of its original value.


b) Time taken for 0.085 M to decrease to 0.055 M


Thus it will take 8.2 minutes until the concentration decreases to 0.055 M
The SI base units and their physical quantities are the metre for measurement of length, the kilogram for mass, the second for time, the ampere for electric current, the kelvin for temperature, the candela for luminous intensity, and the mole for amount of substance.