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blondinia [14]
3 years ago
12

Calculate the equilibrium constant, k, for the reaction shown at 25 °c. fe3 (aq) b(s) 6h2o(l)⟶fe(s) h3bo3(s) 3h3o (aq) the balan

ced reduction half‑reactions for the equation and their respective standard reduction potential values (e∘) are fe3 (aq) 3e−⟶fe(s)h3bo3(s) 3h3o (aq) 3e−⟶b(s) 6h2o(l)e∘e∘
Chemistry
1 answer:
Rainbow [258]3 years ago
3 0

The complete question is ;

Calculate the equilibrium constant, K, for the reaction shown at 25 °C.

Fe3+(aq)+B(s)+6H2O(l)-------->Fe(s)+H3BO3(s)+3H3O+(aq)

The balanced reduction half?reactions for the equation and their respective standard reduction potential values (E?) are

Fe3+(aq)+3e------>Fe(s) E°=-0.04V

H3BO3(s)+3H3O+(aq)+3e------->B(s)+6H2O(l) E°=0.8698 V

Answer:

1.05

Explanation:

E° cell= E°cathode- E°anode

E°cathode = 0.8698 V

E°anode= -0.04V

E°cell=0.8698 V - (-0.04V)

E°cell= 0.9098 V

E°cell= 0.0592/n logK

From the balanced redox reaction equations above, n=3

0.9098 V= 0.0592/3 logK

logK= 0.0217

K= Antilog (0.0217)

K= 1.05

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Answer:

Less than 0.033 M:

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Explanation:

Hello,

In this case, the described equilibrium is:

2A+B\rightarrow 2Z

Thus, the law of mass action is:

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Know, by introducing the change x due to the reaction extent, we can write:

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Which has the following solution:

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But the correct solution is x_3=0.0152M since the other solutions make the equilibrium concentration of Z negative which is not possible. In such a way, its concentration at equilibrium is:

[Z]_{eq}=0.033M-2(0.0153M)

[Z]_{eq}=2.4x10^{-3}M

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Regards.

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3 years ago
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Explanation:

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I'm going to have to infer that you meant "grams" and not "gallons" :-)

Anyways, to find the density, you need to the divide mass over volume (d = m/V).

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