Answer:
ΔH of the reaction is -802.3kJ.
Explanation:
Using Hess's law, you can know ΔH of reaction by the sum of ΔH's of half-reactions.
Using the reactions:
<em>(1) </em>Cgraphite(s)+ 2H₂(g) → CH₄(g) ΔH₁ = −74.80kJ
<em>(2) </em>Cgraphite(s)+ O₂(g) → CO₂(g) ΔH₂ = −393.5k
J
<em>(3) </em>H₂(g) + 1/2 O₂(g) → H₂O(g) ΔH₃ = −241.80kJ
The sum of (2) - (1) produce:
CH₄(g) + O₂(g) → CO₂(g) + 2H₂(g) ΔH' = -393.5kJ - (-74.80kJ) = -318.7kJ
And the sum of this reaction with 2×(3) produce:
CH₄(g) + 2 O₂(g) → CO₂(g) + 2H₂O(g) And ΔH = -318.7kJ + 2×(-241.80kJ) =
<em>-802.3kJ</em>
Answer:-
The reaction of 2-bromopropane reacts with sodium iodide in acetone is an example of Sn2 reaction.
The I - attacks from backside to give the transition state for both.
If we compare the transition state for cyclobromopropane 2-bromopropane then we see in case of cyclobromopropane transition state, one of the H is very close to the incoming I -.
This results in steric strain and less stability of the transition state. Hence 2-bromopropane reacts with sodium iodide in acetone over 104 times faster than bromocyclopropane.
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