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mixer [17]
3 years ago
14

How much heat must be removed from 25.0g of steam at 118.0C in order to form ice at 15C

Chemistry
1 answer:
NemiM [27]3 years ago
3 0

Answer:

-10778.95 J heat must be removed in order to form the ice at 15 °C.

Explanation:

Given data:

mass of steam = 25 g

Initial temperature = 118 °C

Final temperature = 15 °C

Heat released = ?

Solution:

Formula:

q = m . c . ΔT

we know that specific heat of water is 4.186 J/g.°C

ΔT = final temperature - initial temperature

ΔT = 15 °C - 118 °C

ΔT = -103 °C

now we will put the values in formula

q = m . c . ΔT

q = 25 g × 4.186 J/g.°C × -103 °C

q = -10778.95 J

so, -10778.95 J heat must be removed in order to form the ice at 15 °C.

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What is the standard electrode potential for a galvanic cell constructed in the appropriate way from these two half-cells?
____ [38]

E

θ

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=

+

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l

V

Cathode

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Explanation:

Look up the reduction potential for each cell in question on a table of standard electrode potential like this one from Chemistry LibreTexts. [1]

Mg

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a

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l

e

−

→

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(

s

)

−

E

θ

=

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(

a

q

)

+

2

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e

−

→

Ni

(

s

)

−

E

θ

=

−

0.257

l

V

The standard reduction potential

E

θ

resembles the electrode's strength as an oxidizing agent and equivalently its tendency to get reduced. The reduction potential of a Platinum-Hydrogen Electrode under standard conditions (

298

l

K

,

1.00

l

kPa

) is defined as

0

l

V

for reference. [2]

A cell with a high reduction potential indicates a strong oxidizing agent- vice versa for a cell with low reduction potentials.

Two half cells connected with an external circuit and a salt bridge make a galvanic cell; the half-cell with the higher

E

θ

and thus higher likelihood to be reduced will experience reduction and act as the cathode, whereas the half-cell with a lower

E

θ

will experience oxidation and act the anode.

E

θ

(

Ni

2

+

/

Ni

)

>

E

θ

(

Mg

2

+

/

Mg

)

Therefore in this galvanic cell, the

Ni

2

+

/

Ni

half-cell will experience reduction and act as the cathode and the

Mg

2

+

/

Mg

the anode.

The standard cell potential of a galvanic cell equals the standard reduction potential of the cathode minus that of the anode. That is:

E

θ

cell

=

E

θ

(

Cathode

)

−

E

θ

(

Anode

)

E

θ

cell

=

−

0.257

−

(

−

2.372

)

E

θ

cell

=

+

2.115

Indicating that connecting the two cells will generate a potential difference of

+

2.115

l

V

across the two cells.

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