Answer:
(E) changing temperature
Explanation:
Consider the following reversible balanced reaction:
aA+bB⇋cC+dD
If we know the molar concentrations of each of the reaction species, we can find the value of Kc using the relationship:
Kc = ([C]^c * [D]^d) / ([A]^a * [B]^b)
where:
[C] and [D] are the concentrations of the products in the equilibrium; [A] and [B] reagent concentrations in equilibrium; already; b; c and d are the stoichiometric coefficients of the balanced equation. Concentrations are commonly expressed in molarity, which has units of moles / 1
There are some important things to remember when calculating Kc:
- <em>Kc is a constant for a specific reaction at a specific temperature</em>. If you change the reaction temperature, then Kc also changes
- Pure solids and liquids, including solvents, are not considered for equilibrium expression.
- The reaction must be balanced with the written coefficients as the minimum possible integer value in order to obtain the correct value of Kc
Answer:
Explanation:
The polarity of the 3 compounds would be in the order of
Ferrocene < Acetylferrocene < Diacetylferrocene
Your TLC data has to also support this observation . This can be checked by measuring the values of Rf ( Retention factor = distance travelled by solute/solvent ) .The Rf values also has to follow this particular order: -
Ferrocene > acetylferrocene > diacetylferrocene
2) Hexane happens to be a non-polar solvent. The polarity of hexane can be increased if some polar solvents for example, ethyl and methylene chloride etc are added
Therefore, in the increasing order of solvents polarity, we have
Hexane < 1:1 mixture of hexane: methylene chloride < 9:1 mixture of methylene chloride:
3) Chromatographic techniques all have a stationary phase in addition to a mobile phase. In the case of column chromatography, the silica gel will be the stationary phase and the solvent that will be poured will be the mobile phase.
4) The TLC and column chromatography both happen to have the same stationary phase which is the silica gel. Also, the same solvent mixture is used in both the techniques. This makes the result of the 2 to be almost the same. The difference seen between them is that, TLC works against the gravity while on the other hand column chromatography works in the direction of the gravity.
5) The key feature in the IR spectra of the acetylferrocene that will be absent in the spectra of ferrocene is the presence of carbonyl stretching frequency at close to 1700 per cm(cm-1). This peak is easily differentiated between both acetyl ferrocene and ferrocene.
1 mol = 6.023x10^23 number of molecules (Avogadro's number)
1 : 6.023x10^23
X : 4.91x10^22
(6.023x10^23)X = 4.91x10^22
X = 4.91x10^22/6.023x10^23
X = 0.082 Moles
