a scientist mixes to clear substances together and notices the following about the final solution it is cloudy some bubbles are
1 answer:
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Answer:
B. First order, Order with respect to C = 1
Explanation:
The given kinetic data is as follows:
A + B + C → Products
[A]₀ [B]₀ [C]₀ Initial Rate (10⁻³ M/s)
1. 0.4 0.4 0.2 160
2. 0.2 0.4 0.4 80
3. 0.6 0.1 0.2 15
4. 0.2 0.1 0.2 5
5. 0.2 0.2 0.4 20
The rate of the above reaction is given as:
where x, y and z are the order with respect to A, B and C respectively.
k = rate constant
[A], [B], [C] are the concentrations
In the method of initial rates, the given reaction is run multiple times. The order with respect to a particular reactant is deduced by keeping the concentrations of the remaining reactants constant and measuring the rates. The ratio of the rates from the two runs gives the order relative to that reactant.
Order w.r.t A : Use trials 3 and 4
Order w.r.t B : Use trials 2 and 5
Order w.r.t C : Use trials 1 and 2
we know that x = 1 and y = 2, substituting the appropriate values in the above equation gives:
z = 1
Therefore, order w.r.t C = 1
Answer:
a. The second run will be faster.
d. The second run has twice the surface area.
Explanation:
The rate of a reaction is proportional to the surface area of a catalyst. Given the volume (V) of a sphere, we can find its surface area (A) using the following expression.
The area of the 10.0 cm³-sphere is:
The area of each 1.25 cm³-sphere is:
The total area of the 8 1.25cm³-spheres is 8 × 5.61 cm² = 44.9 cm²
The ratio of 8 1.25cm³-sphere to 10.0 cm³-sphere is 44.9 cm²/22.4 cm² = 2.00
Since the surface area is doubled, the second run will be faster.