Explanation:
The oxidation number of Ni is +4
Answer : The entropy change for the surroundings of the reaction is, -198.3 J/K
Explanation :
We have to calculate the entropy change of reaction
.

![\Delta S^o=[n_{NH_3}\times \Delta S^0_{(NH_3)}]-[n_{N_2}\times \Delta S^0_{(N_2)}+n_{H_2}\times \Delta S^0_{(H_2)}]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo%3D%5Bn_%7BNH_3%7D%5Ctimes%20%5CDelta%20S%5E0_%7B%28NH_3%29%7D%5D-%5Bn_%7BN_2%7D%5Ctimes%20%5CDelta%20S%5E0_%7B%28N_2%29%7D%2Bn_%7BH_2%7D%5Ctimes%20%5CDelta%20S%5E0_%7B%28H_2%29%7D%5D)
where,
= entropy of reaction = ?
n = number of moles
= standard entropy of 
= standard entropy of 
= standard entropy of 
Now put all the given values in this expression, we get:
![\Delta S^o=[2mole\times (192.5J/K.mole)]-[1mole\times (191.5J/K.mole)+3mole\times (130.6J/K.mole)]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo%3D%5B2mole%5Ctimes%20%28192.5J%2FK.mole%29%5D-%5B1mole%5Ctimes%20%28191.5J%2FK.mole%29%2B3mole%5Ctimes%20%28130.6J%2FK.mole%29%5D)

Therefore, the entropy change for the surroundings of the reaction is, -198.3 J/K
Answer:
The specific heat capacity of glass is 0.70J/g°C
Explanation:
Heat lost by glass = heat gained by water
Heat lost by glass = mass × specific heat capacity (c) × (final temperature - initial temperature) = 58.5×c×(91.2 - 21.7) = 4065.75c
Heat gained by water = mass × specific heat capacity × (final temperature - initial temperature) = 250×4.2×(21.7 - 19) = 2835
4065.75c = 2835
c = 2835/4065.75 = 0.70J/g°C
An example can be perspiration or even rain.
Hope this helps.