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lesya [120]
3 years ago
14

At 10 K Cp,m(Hg(s)) = 4.64 J K−1 mol−1. Between 10 K and the melting point of Hg(s), 234.3 K, heat capacity measurements indicat

e that the entropy increases by 57.74 J K−1 mol−1. The standard enthalpy of fusion of Hg(s) is 2322 J mol−1 at 234.3 K. Between the melting point and 298.0 K, heat capacity measurements indicate that the entropy increases by 6.85 J K−1 mol−1. Determine the Third-Law standard molar entropy of Hg(l) at 298 K.
Chemistry
1 answer:
umka21 [38]3 years ago
4 0

Answer:

S°m,298K = 85.184 J/Kmol

Explanation:

∴ T = 10 K ⇒ Cp,m(Hg(s)) = 4.64 J/Kmol

∴ 10 K to 234.3 K ⇒ ΔS = 57.74 J/Kmol

∴ T = 234.3 K ⇒ ΔHf = 2322 J/mol

∴ 234.3 K to 298.0 K ⇒ ΔS = 6.85 J/Kmol

⇒ S°m,298K = S°m,0K + ∫CpdT/T(10K) + ΔS(10-234.3) + ΔHf/T(234.3K) + ΔS(234.3-298)

⇒ S°m,298K = 0 + 10.684 J/Kmol + 57.74 J/Kmol + 9.9104 J/Kmol + 6.85 J/kmol

⇒ S°m,298K = 85.184 J/Kmol

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Question 4(Multiple Choice Worth 4 points)
vitfil [10]

Answer:

The quantum number that describes the orientation of an orbital within a sublevel is the magnetic quantum number.

Explanation:

There are four quantum numbers in chemistry. These are the principal quantum number, the angular momentum quantum number, the magnetic quantum number, and the spin quantum number. These all follow these three foundational rules in chemistry.

The Pauli exclusion principle states that if two electrons inhabit the same orbital, they will spin in different directions.

Hund's rule states that if an orbital does not have an electron, an electron will need to fill it first before any of the other orbitals can have two electrons of differing spins.

The Aufbau principle states that all electrons will fill orbitals in an orderly fashion based on the quantum numbers.  An attachment is included of this fill order for your reference.

The four quantum numbers for chemistry are:

The principal quantum number describes the sublevel in which the orbital is located. This occurs at n = 1, 2, 3, etc. all the way to 7.

The angular momentum quantum number describes the orbital that an electron fills. It will refer to the shape and the type of orbital.  

The magnetic quantum number refers to the orientation of an orbital. Based on the angular momentum quantum number, there can be 1, 3, 5, or 7 orientations.

The spin quantum number refers to the Pauli exclusion principle. This number is assigned a negative or positive based on the orientation of the electron.

Therefore, because the magnetic quantum number is the one that refers to <u>the orientation of the orbital</u>, this is our answer.

5 0
3 years ago
In the diagram below, west is to the left, east is to the right, and the observer is looking toward the north. What is the direc
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2 years ago
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What did timbuktu contributed to mali's important as a kingdom
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Which of the following has the smallest radius? <br> A. O^2- <br> B. F^- <br> C. Li^- <br> D. Be^2+
nordsb [41]

Answer : The correct option is, (D) Be^{2+}

Explanation :

Effective nuclear charge : It is defined as the attraction of the protons present in the nucleus of an atom to the outermost electrons.

For ions, the effective nuclear charge changes than the neutral atom.

There are two types of ions:

Cations: They are formed when an atom looses its valence electrons. They are positive ions.

Anions: They are formed when an atom gain electrons in its outermost shell. They are negative ions.

For positive ions, the removal of electron increases the nuclear charge for an outermost electron because the outermost electrons are more strongly attracted by the nucleus. Thus, the effective nuclear charge increases for cations.

From this we conclude that, the size of the cation is smaller than their neutral atom because it has less number of electrons while its nuclear charge remains the same. So, the nucleus attracts the electron more towards itself and leads to the decrease in size.

For negative ions, the addition of electron decreases the nuclear charge for an outermost electron because the outermost electrons are less strongly attracted by the nucleus. Thus, the effective nuclear charge decreases for anions.

From this we conclude that, the size of the anion is greater than their neutral atom because it has more number of electrons while its nuclear charge remains the same. So, the nucleus attracts the electron less towards itself and leads to the increase in size.

Thus, the increasing order of radius of ions will be:

Be^{2+}

Hence, the smallest radius of ion is, Be^{2+}

4 0
4 years ago
A 1.757-g sample of a / alloy was dissolved in acid and diluted to exactly 250.0 mL in a volumetric flask. A 50.00-mL aliquot of
kondor19780726 [428]

Answer:

78.14% Pb²⁺ and 21.86% of Cd²⁺

Explanation:

The first titration involves the reaction of both Pb²⁺ and Cd²⁺

In the second titration, as the buffer is HCN/NaCN, the Cd²⁺ precipitates as Cd(CN)₂ and the only ion that reacts is Pb²⁺

In the first titration:

<em>Moles EDTA = Moles Pb²⁺ and Cd²⁺:</em>

28.89mL = 0.02889L * (0.06950moles / L) = 2.008x10⁻³ moles in the aliquot. In the sample:

2.008x10⁻³ moles * (250.0mL / 50.0mL) =

0.01004 moles = Pb²⁺ + Cd²⁺ <em>(1)</em>

In the second titration:

19.07mL = 0.01907L * (0.06950mol / L) = 1.325x10⁻³ moles Pb²⁺ in the aliquot. In the sample:

1.325x10⁻³ moles Pb²⁺ * (250.0mL / 50.0mL) =

6.626x10⁻³ moles Pb²⁺

That means the moles of Cd²⁺ are:

0.01004 moles = Cd²⁺ + 6.626x10⁻³ moles Cd²⁺

3.413x10⁻³ moles Cd²⁺

The mass of each ion is:

<em>Cd²⁺ -Molar mass: 112.411g/mol-:</em>

3.413x10⁻³ moles Cd²⁺ * (112.411g / mol) =

0.384g of Cd²⁺

<em>Pb²⁺ -Molar mass: 207.2g/mol-:</em>

6.626x10⁻³ moles Pb²⁺ * (207.2g / mol) =

1.373g of Pb²⁺

The percent mass of each ion is:

1.373g Pb²⁺ / 1.757g = 78.14% Pb²⁺

And:

0.384g of Cd²⁺ / 1.757g * 100 = 21.86% of Cd²⁺

4 0
3 years ago
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