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Zanzabum
3 years ago
7

Express the concentration of a 0.0390 M aqueous solution of fluoride, F − , in mass percentage and in parts per million (ppm). A

ssume the density of the solution is 1.00 g/mL.
Chemistry
1 answer:
Vadim26 [7]3 years ago
5 0

Answer:

Mass percentage → 0.074 %

[F⁻] = 741 ppm

Explanation:

Aqueous solution of flouride → [F⁻] = 0.0390 M

It means that in 1L of solution, we have 0.0390 moles of F⁻

We need the mass of solution and the mass of 0.0390 moles of F⁻

Mass of solution can be determined by density:

1g/mL = Mass of solution / 1000 mL

Note: 1L = 1000mL

Mass of solution: 1000 g

Moles of F⁻ → 0.0390 moles . 19g /1 mol = 0.741 g

Mass percentage → (Mass of solute / Mass of solution) . 100

(0.741 g / 1000 g) . 100 = 0.074 %

Ppm = mass of solute . 10⁶ / mass of solution (mg/kg)

0.741 g . 1000 mg/1g = 741 mg

1000 g . 1 kg/1000 g = 1kg

741 mg/1kg = 741 ppm

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<u>Answer:</u> The molecular formula for the menthol is C_{10}H_{20}O

<u>Explanation:</u>

The chemical equation for the combustion of hydrocarbon having carbon, hydrogen and oxygen follows:

C_xH_yO_z+O_2\rightarrow CO_2+H_2O

where, 'x', 'y' and 'z' are the subscripts of Carbon, hydrogen and oxygen respectively.

We are given:

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Mass of H_2O=0.1159g

We know that:

Molar mass of carbon dioxide = 44 g/mol

Molar mass of water = 18 g/mol

  • <u>For calculating the mass of carbon:</u>

In 44g of carbon dioxide, 12 g of carbon is contained.

So, in 0.2829 g of carbon dioxide, \frac{12}{44}\times 0.2829=0.077g of carbon will be contained.

  • <u>For calculating the mass of hydrogen:</u>

In 18g of water, 2 g of hydrogen is contained.

So, in 0.1159 g of water, \frac{2}{18}\times 0.1159=0.0129g of hydrogen will be contained.

  • Mass of oxygen in the compound = (0.1005) - (0.077 + 0.0129) = 0.0106 g

To formulate the empirical formula, we need to follow some steps:

  • <u>Step 1:</u> Converting the given masses into moles.

Moles of Carbon = \frac{\text{Given mass of Carbon}}{\text{Molar mass of Carbon}}=\frac{0.077g}{12g/mole}=0.0064moles

Moles of Hydrogen = \frac{\text{Given mass of Hydrogen}}{\text{Molar mass of Hydrogen}}=\frac{0.0129g}{1g/mole}=0.0129moles

Moles of Oxygen = \frac{\text{Given mass of oxygen}}{\text{Molar mass of oxygen}}=\frac{0.0106g}{16g/mole}=0.00066moles

  • <u>Step 2:</u> Calculating the mole ratio of the given elements.

For the mole ratio, we divide each value of the moles by the smallest number of moles calculated which is 0.00066 moles.

For Carbon = \frac{0.0064}{0.00066}=9.69\approx 10

For Hydrogen  = \frac{0.0129}{0.00064}=19.54\approx 20

For Oxygen  = \frac{0.00066}{0.00066}=1

  • <u>Step 3:</u> Taking the mole ratio as their subscripts.

The ratio of C : H : O = 10 : 20 : 1

Hence, the empirical formula for the given compound is C_{10}H_{20}O_1=C_{10}H_{20}O

For determining the molecular formula, we need to determine the valency which is multiplied by each element to get the molecular formula.

The equation used to calculate the valency is :

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Mass of empirical formula = 156 g/mol

Putting values in above equation, we get:

n=\frac{156.27g/mol}{156g/mol}=1

Multiplying this valency by the subscript of every element of empirical formula, we get:

C_{(1\times 10)}H_{(1\times 20)}O_{(1\times 1)}=C_{10}H_{20}O

Thus, the molecular formula for the menthol is C_{10}H_{20}O

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