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irinina [24]
3 years ago
13

Commercial grade HCl solutions are typically 39.0% (by mass) HCl in water. Determine the molality of the HCl, if the solution ha

s a density of 1.20 g/mL
Chemistry
1 answer:
marta [7]3 years ago
8 0

Molality of the solution is defined as the number of moles of a substance dissolved divided by the mass of the solvent:

Molality = number of moles / solvent mass

From the concentration of 39% (by mass) of HCl in water, we construct the following  reasoning:

in 100 g solution we have 39 g hydrochloric acid (HCl)

number of moles  = mass / molecular weight

number of moles of HCl = 39 / 36.5 = 1.07 moles

solvent (water) mass = solution mass - hydrochloric acid mass

solvent (water) mass = 100 - 39 = 61 g

Now we can determine the molality:

molality = 1.07 moles / 61 g = 0.018

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  • Problem 1: 1.85atm
  • Problem 2: 110mL
  • Problem 3: 290 mL
  • Problem 4: 1.14 atm

Explanation:

Problem 1

<u>1. Data</u>

<u />

a) P₁ = 3.25atm

b) V₁ = 755mL

c) P₂ = ?

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r) T = 65ºC

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Since the temeperature is constant you can use Boyle's law for idial gases:

          PV=constant\\\\P_1V_1=P_2V_2

<u>3. Solution</u>

Solve, substitute and compute:

         P_1V_1=P_2V_2\\\\P_2=P_1V_1/V_2

        P_2=3.25atm\times755mL/1325mL=1.85atm

Problem 2

<u>1. Data</u>

<u />

a) V₁ = 125 mL

b) P₁ = 548mmHg

c) P₁ = 625mmHg

d) V₂ = ?

<u>2. Formula</u>

You assume that the temperature does not change, and then can use Boyl'es law again.

          P_1V_1=P_2V_2

<u>3. Solution</u>

This time, solve for V₂:

           P_1V_1=P_2V_2\\\\V_2=P_1V_1/P_2

Substitute and compute:

        V_2=548mmHg\times 125mL/625mmHg=109.6mL

You must round to 3 significant figures:

        V_2=110mL

Problem 3

<u>1. Data</u>

<u />

a) V₁ = 285mL

b) T₁ = 25ºC

c) V₂ = ?

d) T₂ = 35ºC

<u>2. Formula</u>

At constant pressure, Charle's law states that volume and temperature are inversely related:

         V/T=constant\\\\\\\dfrac{V_1}{T_1}=\dfrac{V_2}{T_2}

The temperatures must be in absolute scale.

<u />

<u>3. Solution</u>

a) Convert the temperatures to kelvins:

  • T₁ = 25 + 273.15K = 298.15K

  • T₂ = 35 + 273.15K = 308.15K

b) Substitute in the formula, solve for V₂, and compute:

        \dfrac{V_1}{T_1`}=\dfrac{V_2}{T_2}\\\\\\\\\dfrac{285mL}{298.15K}=\dfrac{V_2}{308.15K}\\\\\\V_2=308.15K\times285mL/298.15K=294.6ml

You must round to two significant figures: 290 ml

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<u>1. Data</u>

<u />

a) P = 865mmHg

b) Convert to atm

<u>2. Formula</u>

You must use a conversion factor.

  • 1 atm = 760 mmHg

Divide both sides by 760 mmHg

       \dfrac{1atm}{760mmHg}=\dfrac{760mmHg}{760mmHg}\\\\\\1=\dfrac{1atm}{760mmHg}

<u />

<u>3. Solution</u>

Multiply 865 mmHg by the conversion factor:

    865mmHg\times \dfrac{1atm}{760mmHg}=1.14atm\leftarrow answer

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