A solution is saturated when it contains the maximum amount of solute for the given solvent.

For the reaction A+B+C→D+E, the initial reaction rate was measured for various initial concentrations of reactants. The followin

erastovalidia [21]

Answer : The initial rate for a reaction will be $3.4\times 10^{-3}Ms^{-1}$

Explanation :

Rate law is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.

For the given chemical equation:

$A+B+C\rightarrow D+E$

Rate law expression for the reaction:

$\text{Rate}=k[A]^a[B]^b[C]^c$

where,

a = order with respect to A

b = order with respect to B

c = order with respect to C

Expression for rate law for first observation:

$6.0\times 10^{-5}=k(0.20)^a(0.20)^b(0.20)^c$ ....(1)

Expression for rate law for second observation:

$1.8\times 10^{-4}=k(0.20)^a(0.20)^b(0.60)^c$ ....(2)

Expression for rate law for third observation:

$2.4\times 10^{-4}=k(0.40)^a(0.20)^b(0.20)^c$ ....(3)

Expression for rate law for fourth observation:

$2.4\times 10^{-4}=k(0.40)^a(0.40)^b(0.20)^c$ ....(4)

Dividing 1 from 2, we get:

$\frac{1.8\times 10^{-4}}{6.0\times 10^{-5}}=\frac{k(0.20)^a(0.20)^b(0.60)^c}{k(0.20)^a(0.20)^b(0.20)^c}\\\\3=3^c\\c=1$

Dividing 1 from 3, we get:

$\frac{2.4\times 10^{-4}}{6.0\times 10^{-5}}=\frac{k(0.40)^a(0.20)^b(0.20)^c}{k(0.20)^a(0.20)^b(0.20)^c}\\\\4=2^a\\a=2$

Dividing 3 from 4, we get:

$\frac{2.4\times 10^{-4}}{2.4\times 10^{-4}}=\frac{k(0.40)^a(0.40)^b(0.20)^c}{k(0.40)^a(0.20)^b(0.20)^c}\\\\1=2^b\\b=0$

Thus, the rate law becomes:

$\text{Rate}=k[A]^2[B]^0[C]^1$

Now, calculating the value of 'k' by using any expression.

Putting values in equation 1, we get:

$6.0\times 10^{-5}=k(0.20)^2(0.20)^0(0.20)^1$

$k=7.5\times 10^{-3}M^{-2}s^{-1}$

Now we have to calculate the initial rate for a reaction that starts with 0.75 M of reagent A and 0.90 M of reagents B and C.

$\text{Rate}=k[A]^2[B]^0[C]^1$

$\text{Rate}=(7.5\times 10^{-3})\times (0.75)^2(0.90)^0(0.90)^1$

$\text{Rate}=3.4\times 10^{-3}Ms^{-1}$

Therefore, the initial rate for a reaction will be $3.4\times 10^{-3}Ms^{-1}$

8 0

2 years ago

Consider the following equilibrium systems: A⇌2B ΔH o =20.0 kJ/mol Reaction 1 A+B⇌C ΔH o =−5.4 kJ/mol Reaction 2 A⇌B ΔH o =0.0 k

galina1969 [7]

Answer:

Reaction 1: Kc increases

Reaction 2: Kc decreases

Reaction 3: The is no change

Explanation:

Let us consider the following reactions:

Reaction 1: A ⇌ 2B ΔH° = 20.0 kJ/mol

Reaction 2: A + B ⇌ C ΔH° = −5.4 kJ/mol

Reaction 3: 2A⇌ B ΔH° = 0.0 kJ/mol

To predict what will happen when the temperature is raised we need to take into account Le Chatelier Principle: when a system at equilibrium suffers a perturbation, it will shift its equilibrium to counteract such perturbation. This means that <em>if the temperature is raised (perturbation), the system will react to lower the temperature.</em>

Reaction 1 is endothermic (ΔH° > 0). If the temperature is raised the system will favor the forward reaction to absorb heat and lower the temperature, thus increasing the value of Kc.

Reaction 2 is exothermic (ΔH° < 0). If the temperature is raised the system will favor the reverse reaction to absorb heat and lower the temperature, thus decreasing the value of Kc.

Reaction 3 is not endothermic nor exothermic (ΔH° = 0) so an increase in the temperature will have no effect on the equilibrium.

8 0

2 years ago

Pls solve<br>question attached as image<br>

patriot [66]

Answer:

a) formula for citric acid is - C6 H8 o7

b) lime water turns opaque after adding co2 due to the formation of calcium carbonate.

c) reaction 3 is displacement reaction where a high reactive metal displace a less reactive from its salt solution.

d) reaction 1) is combination reaction where two reactant combines to give a single product whereas reaction 2) is decomposition reaction where a single reactant splits into more that 1 products.

8 0

2 years ago

Which would be attracted most to a magnet?

Debora [2.8K]

Either iron or metal

8 0

3 years ago

Nitrogen monoxide, NO, is formed in automobile exhaust by the reaction of nitrogen and oxygen in the air: N2 (g) + O2 (g) ↔ NO (

Solnce55 [7]

Answer:

The equilibrium concentration of NO is 0.001335 M

Explanation:

Step 1: Data given

The equilibrium constant Kc is 0.0025 at 2127 °C

An equilibrium mixture contains 0.023M N2 and 0.031 M O2,

Step 2: The balanced equation

N2(g) + O2(g) ↔ 2NO(g)

Step 3: Concentration at the equilibrium

[N2] = 0.023 M

[O2] = 0.031 M

Kc = 0.0025 = [NO]² / [N2][O2]

Kc = 0.0025 = [NO]² / (0.023)(0.031)

[NO] = 0.001335 M

The equilibrium concentration of NO is 0.001335 M

6 0

3 years ago