In general, for most things, A would be correct (Any time of the day). It kind of depends on what you ar collecting the sample for. I think the earlier the better but it doesnt usually matter.
Thats actually not true the pancreas is for filtering out the sugars in your body it helps the kidneys filter toxins out of your body (it can also help break down food but that's not the main purpose) and if a person is a diabetic it won't be able to work with the kidneys to filter out the toxins and sugars. Thats when they have to use the Insulin to help it filter it out. (My mom has diabetes so i know this) <span />