Answer:
Molecularity of the rate determining step = 2
Explanation:
Step 1 (slow): H₂O₂ + I⁻ -----> H₂O + OI⁻
Step 2 (fast): H₂O₂ + OI⁻ -----> H₂O + O₂ + I⁻
The rate determining step in a reaction mechanism is also considered as slowest step.
Slowest step is also considered its highest activation energy in energy profile diagram.
In this case intermediate (IO⁻) is formed.
Step 1 considered as a slowest step.
So, Rate = K [H₂O₂][I⁻]
Molecularity = 2
Q: A
according to this formula, we can get the mole fraction of water (n):
P(solu) = n Pv(water)
when we have Pv(solu) = 22.8 and Pv(water) = 23.8 so by substitution:
22.8 = n * 23.8
n= 0.958
- we need to get the moles of glucose:
moles of water = 500 g(mass weight) / 18 (molar weight)= 27.7 mol
n = moles of water / ( moles of water + moles of glucose)
0.958 = 27.7 / ( 27.7+ moles of glucose)
0.958 moles of glucose + 26.5 = 27.7
0.968 moles of glucose = 1.2
moles of glucose = 1.253 mol
∴ the mass of glucose = no.of glucose moles x molar mass
= 1.253 x 180 = 225.5 g
Q: B
here we also need to get n (mole fraction of water )by using this formula:
Pv(solu) = n Pv(water)
when we have Pv(solu)=132 & Pv(water)=150 so, by substition:
132= n * 150
n = 0.88
so, mole fraction of solution = 1 - 0.88 = 0.12
and we can get after that the moles of water = (mass weight / molar mass)
- no.moles of water = 85 g / 18 g/mol = 4.7 moles
- total moles in solution = moles of water / moles fraction of water
= 4.7 / 0.88 = 5.34 moles
∴ moles of the solution = total moles in solu - moles of water
= 5.34 - 4.7 = 0.64 moles solute
∴ the molar mass of the solute = mass weight of solute / no.of moles of solute
= 53.8 / 0.64 = 84 g/mole
Q: C
moles of urea (NH2)2 CO = mass weight / molar mass
= 4.49 g / 60 g /mol
= 0.07 mol
moles of methanol = mass weight / molar mass
= 39.9 g / 32 g/mol = 1.25 mol
moles fraction of methanol = moles of methanol / (moles of methanol + moles of urea )
moles fraction of methanol = 1.25 / ( 1.25+0.07) = 0.95
by substitution in Pv formula we will be able to get the vapour pressure of the solu :
Pv(solu) = n P°v
Pv(solu) = 0.95 * 89 mm Hg
∴Pv(solu) = 84.55 mmHg
Answer:
Burning wood
Explanation:
the fire releases heat into the air from the burning wood
For example, ionic compounds, which are very polar, are often soluble in the polar solvent water. Nonpolar substances are likely to dissolve in nonpolar solvents. For example, nonpolar molecular substances are likely to dissolve in hexane, a common nonpolar solvent.
Answer:
NO would form 65.7 g.
H₂O would form 59.13 g.
Explanation:
Given data:
Moles of NH₃ = 2.19
Moles of O₂ = 4.93
Mass of NO produced = ?
Mass of produced H₂O = ?
Solution:
First of all we will write the balance chemical equation,
4NH₃ + 5O₂ → 4NO + 6H₂O
Now we will compare the moles of NO and H₂O with ammonia from balanced chemical equation:
NH₃ : NO NH₃ : H₂O
4 : 4 4 : 6
2.19 : 2.19 2.19 : 6/4 × 2.19 = 3.285 mol
Now we will compare the moles of NO and H₂O with oxygen from balanced chemical equation:
O₂ : NO O₂ : H₂O
5 : 4 5 : 6
4.93 : 4/5×4.93 = 3.944 mol 4.93 : 6/5 × 4.93 = 5.916 mol
we can see that moles of water and nitrogen monoxide produced from the ammonia are less, so ammonia will be limiting reactant and will limit the product yield.
Mass of water = number of moles × molar mass
Mass of water = 3.285 mol × 18 g/mol
Mass of water = 59.13 g
Mass of nitrogen monoxide = number of moles × molar mass
Mass of nitrogen monoxide = 2.19 mol × 30 g/mol
Mass of nitrogen monoxide = 65.7 g
