Answer:
a. ΔH⁸ = -1420 kJ/mol b. ΔH⁸ = -1144.84 kJ/mol
Explanation:
a.
C₂H₄ (g) + 3 O₂ (g) ------------------------ 4 CO₂ (g) + 2 H₂O (l) ΔH⁸ = ?
ΔH⁸f kJmol 52.47 0 -399.5 -285.83
ΔH⁸ = 2(-399.5) + 2 (-285.83) - (52.47)
ΔH⁸ = -1420 kJ/mol
b.
H₂S (g) + 3 O₂ (g) ---------------------- 2 H₂O (l) + 2 SO₂ (g)
ΔH⁸f kJmol -20.50 0 -285.83 -296.84
ΔH⁸ = 2(-285.83) + 2 (-296.84) - (-20.50)
ΔH⁸ = -1144.84 kJ/mol
Answer:see attached image
Explanation:
In organic chemistry, a product may be kinetically or thermodynamically favoured. A kinetically favours product forms faster, it may not necessarily be the more stable product. The thermodynamically favoured product forms at a slower rate but is more stable. Often times, the kinetically favoured product rearranges itself to form the thermodynamically favoured product at equilibrium. The endo product of the Diels Alder reaction mentioned in the question is first formed (kinetically favoured) but rearranges to form the exo product (thermodynamically favoured) at equilibrium. This is clear shown in the reaction mechanism attached below.
The answer of the question is 9075