Answer:
a) C6H5COOH + H2O ↔ H3O+ + C6H5COO-
b) [ H3O+ ] = 2.517 E-3 M
c) pH = 2.599
Explanation:
a) balanced equation:
C6H5COOH + H2O ↔ H3O+ + C6H5COO-
⇒ Ka = ( [ H3O+ ] * [ C6H5COO- ] ) / [ C6H5COOH ] = 6.5 E-5
mass balance:
0.10 m = [ C6H5COO- ] + [ C6H5COOH ].....(1)
charge balance:
[ H3O+ ] = [ C6H5COO- ] + [ OH- ] .......[ OH- ] : comes from water, it's not significant
⇒ [ H3O+ ] = [ C6H5COO- ] .........(2)
b) (2) in (1):
⇒ 0.10 M = [ H3O+ ] + [ C6H5COOH ]
⇒ [ C6H5COOH ] = 0.10 - [ H3O+ ]
⇒ Ka = [ H3O+ ]² / ( 0.1 - [ H3O+ ] ) = 6.5 E-5
⇒ [ H3O+ ]² + 6.5 E-5 [ H3O+ ] - 6.5 E-6 = 0
⇒ [ H3O+ ] = 2.517 E-3 M
c) pH = - log [ H3O+ ]
⇒ pH = - Log ( 2.517 E-3 )
⇒ pH = 2.599
The molality is calculated using the following rule:
molality = number of moles of solute / kg of solvent
From the periodic table:
molar mass of lithium = 6.941 gm
molar mass of chlorine = 35.453 gm
molar mass of LiCl = 6.941 + 35.453 = 42.394 gm
number of moles found in 42 gm = mass / molar mass = 42 / 42.394 = 0.99
molality = 0.99 / 3.6 = 0.275 m
Answer:
The given statement - The main criterion for sigma bond formation is that the two bonded atoms have valence orbitals with lobes that point directly at each other along the line between the two nuclei , is <u>True.</u>
Explanation:
The above statement is correct , because the sigma bond is produced by the head on overlapping, the orbitals should all point in the same direction.
<u>SIGMA BONDS -</u> Sigma bonds (bonds) are the strongest type of covalent chemical bond in chemistry. They're made up of atomic orbitals that collide head-on. For diatomic molecules, sigma bonding is best characterized using the language and tools of symmetry groups.
Head-on overlapping of atomic orbitals produces sigma bonds. The concept of sigma bonding is expanded to include bonding interactions where a single lobe of one orbital overlaps with a single lobe of another. Propane, for example, is made up of ten sigma bonds, one for each of the two CC bonds and one for each of the eight CH bonds.
Hence , the answer is true .
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<u>Answer:</u> The equilibrium concentration of CO is 0.243 atm
<u>Explanation:</u>
We are given:
Initial partial pressure of carbon dioxide = 0.902 atm
As, carbon dioxide is present initially. This means that the reaction is proceeding backwards.
For the given chemical equation:
<u>Initial:</u> 0.902
<u>At eqllm:</u> 3x (0.902-3x)
The expression of 
for above equation follows:
We are given:
Putting values in above equation, we get:
So, equilibrium concentration of CO = 3x = (3 × 0.0810) = 0.243atm[/tex]
Hence, the equilibrium concentration of CO is 0.243 atm
