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galben [10]
3 years ago
8

For the reaction: PCl5(g) ⇌ PCl3(g) + Cl2(g) at 600.0 K, the equilibrium constant is 11.5. Suppose that 1.500 g of PCl5 (MW=208.

22 g/mol) is placed in an evacuated 500.0 mL bulb, which is then heated to 600.0 K. What is the total pressure (in atm) in the bulb at equilibrium?
Chemistry
1 answer:
spayn [35]3 years ago
8 0

Answer:

1.418688 atm

Explanation:

(a)  Moles of PCl5 = mass / molar mass

                      =1.5 g / 208.22 g/mol

                     = 0.0072 moles

Also given,

T = 600 K

V = 0.500 L

Pressure of PCl5, P = nRT / V

                             = 0.0072 mol×0.0821 L-atm / (mol.K)×600 K / 0.500 L

                             = 0.709344 atm

(b)  PCl5(g) ⇄ PCl3(g) + Cl2(g)

Initial               0.965         0               0

Change               -x            +x             +x

Equilibrium (0.709344 -x)         x               x

K_p = 11.5 = x×x / (0.965 -x)

solving, we get x = 0.67027

So partial pressure of PCl5 at equilibrium = 0.709344 - 0.67027 = 0.039074 atm

(c)   Partial pressure of PCl3 = Cl2 = 0.709344 atm

So total pressure = 0.709344+0.039074+ 0.67027= 1.418688 atm

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Considering the definition of dilution, the molarity of a solution prepared by diluting 7.0 mL of 4.0 M solution to a volume of 30 mL is 0.93 mL.

<h3>What is diluion</h3>

First of all, you have to know that when it is desired to prepare a less concentrated solution from a more concentrated one, it is called dilution.

Dilution is the process of reducing the concentration of solute in solution, which is accomplished by simply adding more solvent to the solution at the same amount of solute.

In a dilution the amount of solute does not change, but as more solvent is added, the concentration of the solute decreases, as the volume (and weight) of the solution increases.

A dilution is mathematically expressed as:

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where

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  • Vi: initial volume
  • Cf: final concentration
  • Vf: final volume

<h3>Molarity of the solution in this case</h3>

In this case, you know:

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Replacing in the definition of dilution:

4 M× 7 mL= Cf× 30 mL

Solving:

(4 M× 7 mL)÷ 30 mL= Cf

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In summary, the molarity of a solution prepared by diluting 7.0 mL of 4.0 M solution to a volume of 30 mL is 0.93 mL.

Learn more about dilution:

brainly.com/question/20113402

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