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galben [10]
3 years ago
8

For the reaction: PCl5(g) ⇌ PCl3(g) + Cl2(g) at 600.0 K, the equilibrium constant is 11.5. Suppose that 1.500 g of PCl5 (MW=208.

22 g/mol) is placed in an evacuated 500.0 mL bulb, which is then heated to 600.0 K. What is the total pressure (in atm) in the bulb at equilibrium?
Chemistry
1 answer:
spayn [35]3 years ago
8 0

Answer:

1.418688 atm

Explanation:

(a)  Moles of PCl5 = mass / molar mass

                      =1.5 g / 208.22 g/mol

                     = 0.0072 moles

Also given,

T = 600 K

V = 0.500 L

Pressure of PCl5, P = nRT / V

                             = 0.0072 mol×0.0821 L-atm / (mol.K)×600 K / 0.500 L

                             = 0.709344 atm

(b)  PCl5(g) ⇄ PCl3(g) + Cl2(g)

Initial               0.965         0               0

Change               -x            +x             +x

Equilibrium (0.709344 -x)         x               x

K_p = 11.5 = x×x / (0.965 -x)

solving, we get x = 0.67027

So partial pressure of PCl5 at equilibrium = 0.709344 - 0.67027 = 0.039074 atm

(c)   Partial pressure of PCl3 = Cl2 = 0.709344 atm

So total pressure = 0.709344+0.039074+ 0.67027= 1.418688 atm

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Now , there are 4 types of sublevels: s, p , d and f . These sublevels have orbital which are spaces with high probability of having an electron and each orbital can have maximum 2 electrons.

Therefore,

s-sublevel has 1 orbital - it can have maximum 2 electrons.

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Hence, the acsending order of sublevels in terms of maximum number of electrons is:

<h2>s < p < d < f</h2>
3 0
3 years ago
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How many molecules are in 145.5 grams of Be(OH)2
Zanzabum

Answer:

2.04 x 10²⁴ molecules

Explanation:

Given parameters:

Mass of Be(OH)₂ = 145.5g

To calculate the number of molecules in this mass of Be(OH)₂ we follow the following steps:

>> Calculate the number of moles first using the formula below:

Number of moles = mass/molarmass

Since we have been given the mass, let us derive the molar mass of Be(OH)₂

Atomic mass of Be = 9g

O = 16g

H = 1g

Molar Mass = 9 + 2(16 + 1)

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>>> We know that a mole is the amount of substance that contains Avogadro’s number of particles. The particles can be atoms, molecules, particles etc. Therefore we use the expression below to determine the number of molecules in 3.38mol of Be(OH)₂:

Number of

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Number of molecules= 3.38 x 6.02 x 10²³

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3 0
3 years ago
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moles  =  mass/molar   mass

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Answer:

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Explanation:

The correct answer is - There is no shift in the state.

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where Q, is the reaction Quotient

6 0
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