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ki77a [65]
3 years ago
13

Complete the dissociation reaction and the corresponding Ka equilibrium expression for each of the following acids in water. (Ty

pe your answer using the format [NH4]+ for NH4+ and [Ni(CN)4]2- for Ni(CN)42-. Use the lowest possible coefficients.)
(A) HC2H3O2
HC2H3O2(aq) (twosidedarrow) [ ]H+(aq) + [ ] [ ](aq)
Ka = [ ][ ] / [ ]
(B) Co(H2O)63+
Co(H2O)63+(aq) (twosidedarrow) [ ]H+(aq) +[ ][ ](aq)
Ka = [ ][ ] / [ ]
(C) CH3NH3+
CH3NH3+(aq) (twosidedarrow) [ ]H+(aq) +[ ][ ](aq)
Ka = [ ][ ] / [ ]
Chemistry
1 answer:
anastassius [24]3 years ago
3 0

Answer :

(A) The dissociation reaction of HC_2H_3O_2 will be:

HC_2H_3O_2(aq)\rightleftharpoons H^+(aq)+C_2H_3O_2^-(aq)

The equilibrium expression :

K_a=\frac{[H^+][C_2H_3O_2^-]}{[HC_2H_3O_2]}

(B) The dissociation reaction of Co(H_2O)_6^{3+} will be:

Co(H_2O)_6^{3+}(aq)\rightleftharpoons H^+(aq)+Co(H_2O)_5(OH)^{2+}(aq)

The equilibrium expression :

K_a=\frac{[H^+][Co(H_2O)_5(OH)^{2+}]}{[Co(H_2O)_6^{3+}]}

(C) The dissociation reaction of CH_3NH_3^+ will be:

CH_3NH_3^+(aq)\rightleftharpoons H^+(aq)+CH_3NH_2(aq)

The equilibrium expression :

K_a=\frac{[H^+][CH_3NH_2]}{[CH_3NH_3^+]}

Explanation :

Equilibrium constant : It is defined as the equilibrium constant. It is defined as the ratio of concentration of products to the concentration of reactants.

The equilibrium expression for the reaction is determined by multiplying the concentrations of products and divided by the concentrations of the reactants and each concentration is raised to the power that is equal to the coefficient in the balanced reaction.

As we know that the concentrations of pure solids and liquids are constant that is they do not change. Thus, they are not included in the equilibrium expression.

(A) The dissociation reaction of HC_2H_3O_2 will be:

HC_2H_3O_2(aq)\rightleftharpoons H^+(aq)+C_2H_3O_2^-(aq)

The equilibrium expression of HC_2H_3O_2 will be:

K_a=\frac{[H^+][C_2H_3O_2^-]}{[HC_2H_3O_2]}

(B) The dissociation reaction of Co(H_2O)_6^{3+} will be:

Co(H_2O)_6^{3+}(aq)\rightleftharpoons H^+(aq)+Co(H_2O)_5(OH)^{2+}(aq)

The equilibrium expression of Co(H_2O)_6^{3+} will be:

K_a=\frac{[H^+][Co(H_2O)_5(OH)^{2+}]}{[Co(H_2O)_6^{3+}]}

(C) The dissociation reaction of CH_3NH_3^+ will be:

CH_3NH_3^+(aq)\rightleftharpoons H^+(aq)+CH_3NH_2(aq)

The equilibrium expression of CH_3NH_3^+ will be:

K_a=\frac{[H^+][CH_3NH_2]}{[CH_3NH_3^+]}

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A 3.4 g sample of an unknown monoprotic organic acid composed of C,H, and O is burned in air to produce 8.58 grams of carbon dio
Pavlova-9 [17]

Answer:

C_7H_6O_2

Explanation:

Hello there!

In this case, we can divide the problem in three stages: (1) determine the empirical formula with the combustion analysis, (2) compute the molar mass of acid via the moles of the acid in the neutralization and (3) determine the molecular formula.

(1) In this case, since 8.58 g of carbon dioxide are released, we can first compute the moles of carbon in the compound:

n_C=8.58gCO_2*\frac{1molCO_2}{44.01gCO_2}*\frac{1molC}{1molCO_2}=0.195molC

And the moles of hydrogen due to the produced 1.50 grams of water:

n_H=1.50gH_2O*\frac{1molH_2O}{18.02gH_2O}*\frac{2molH}{1molH_2O}  =0.166molH

Next, to compute the mass and moles of oxygen, we need to use the initial 3.4 g of the acid:

m_O=3.4g-0.195molC*\frac{12.01gC}{1molC}-0.166molH*\frac{1.01gH}{1molH} =0.89gO\\\\n_O=0.89gO*\frac{1molO}{16.0gO}=0.0556molO

Thus, the subscripts in the empirical formula are:

C=\frac{0.195}{0.0556}=3.5 \\\\H=\frac{0.166}{0.0556}=3\\\\O=\frac{0.0556}{0.0556}=1\\\\C_7H_6O_2

As they cannot be fractions.

(2) In this case, since the acid is monoprotic, we can compute the moles by multiplying the concentration and volume of KOH:

n_{KOH}=0.279L*0.1mol/L\\\\n_{KOH}=0.0279mol

Which are equal to the moles of the acid:

n_{acid}=0.0279mol

And the molar mass:

MM_{acid}=\frac{3.4g}{0.0279mol} =121.86g/mol

(3) Finally, since the molar mass of the empirical formula is:

7*12.01 + 6*1.01 + 2*16.00 = 122.13 g/mol

Thus, since the ratio of molar masses is 122.86/122.13 = 1, we infer that the empirical formula equals the molecular one:

C_7H_6O_2

Best regards!

8 0
3 years ago
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