solution:
The quoted atomic mass on the Periodic Table is the WEIGHTED average of the individual isotopic masses. The higher the isotopic percentage, the MORE that isotope will contribute to the isotopic mass. For this reason, most masses that are quoted on the Table are non-integral.
By way of example we could look to the hydrogen atom. The VAST majority of hydrogen atoms (in this universe) are the protium isotope. i.e. 1H, whose nuclei contain JUST the defining proton. There is a smaller percentage (>1%) of hydrogen atoms WITH one NEUTRON in their nuclei to give the deuterium isotope. i.e. 2H, and because this is relatively cheap, and easily incorporated into a molecule, deuterium labelling is routinely used in analysis.
And there is even a smaller percentage of hydrogen atoms with TWO NEUTRONS in their nuclei, to give the tritium isotope. i.e. 3H. The weighted average of the isotopic percentages gives 
Answer:
Explanation:
(a) Part 1:
reaction. This is a nucleophilic substitution reaction in which we have two steps. Firstly, chlorine, a good leaving group, leaves the carbon skeleton to form a relatively stable secondary carbocation. This carbocation is then attacked by the hydroxide anion, our nucleophile, to form the final product.
To summarize, this mechanism takes places in two separate steps. The mechanism is attached below.
Part 2:
reaction. This is a nucleophilic substitution reaction in which we have one step. Our nucleophile, hydroxide, attacks the carbon and then chlorine leaves simultaneously without an intermediate carbocation being formed.
The mechanism is attached as well.
(b) The rate determining step is the slow step. Formation of the carbocation has the greatest activation energy, so this is our rate determining step for
. For
, we only have one step, so the rate determining step is the attack of the nucleophile and the loss of the leaving group.
Answer:
a) increases
b) decreases
c) does not change
d) increases
Explanation:
The vapour pressure of a liquid is dependent on;
I) the magnitude of intermolecular forces
II) the temperature of the liquid
Hence, when any of these increases, the vapour pressure increases likewise.
Similarly, the boiling point of a liquid depends on the magnitude of intermolecular forces present because as intermolecular forces increases, more energy is required to break intermolecular bonds.
Lastly, increase in surface area of a liquid does not really affect it's vapour pressure.
<span>V = 24.0 mL + (35.2 g)(mL/10.5g) = I think i'm not all that sure but I think its this.</span>