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geniusboy [140]
4 years ago
11

The ph of an acid solution is 6.20. Calculate the ka for the acid. The acid concentration is 0.010 m.

Chemistry
1 answer:
djverab [1.8K]4 years ago
7 0

Answer:

620

Explanation:

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Which of the following is an exothermic reaction?
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What occurs during one half-life?
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Please help me equalize: PbO2 + MnSO4 + HNO3 = HMnO4 + PbSO4 + Pb(NO3)2 + H2O
Feliz [49]

Answer:

5PbO₂ + 2MnSO₄ + 6HNO₃ ⟶ 2PbSO₄ + 3Pb(NO₃)₂ + 2HMnO₄+ 2H₂O

Explanation:

PbO₂ + MnSO₄ + HNO₃ ⟶ HMnO₄ + PbSO₄ + Pb(NO₃)₂ + H₂O

It will be easiest to balance this equation by the ion-electron method.

1. Write the ionic equation

PbO₂ + Mn²⁺ + SO₄²⁻ + H⁺ + NO₃⁻ ⟶ H⁺ + MnO₄⁻ + Pb²⁺ + SO₄²⁻ + Pb²⁺ + NO₃⁻ + H₂O

2. Eliminate H⁺, H₂O, and spectator ions

PbO₂ + Mn²⁺ ⟶ MnO₄⁻ + Pb²⁺  

3. Separate the skeleton equation into two half-reactions.

PbO₂  ⟶ Pb²⁺  

Mn²⁺ ⟶ MnO₄⁻

4. Balance all atoms other than H and O

Done

5. Balance O by adding water molecules to the deficient side

           PbO₂  ⟶ Pb²⁺ + 2H₂O

Mn²⁺ + 4H₂O ⟶ MnO₄⁻

6. Balance H by adding H⁺ ions to the deficient side.

  PbO₂+ 4H⁺ ⟶ Pb²⁺ + 2H₂O

Mn²⁺ + 4H₂O ⟶ MnO₄⁻ + 8H⁺

7. Balance charge by adding electrons to the deficient side.

PbO₂+ 4H⁺ + 2e⁻ ⟶ Pb²⁺ + 2H₂O

     Mn²⁺ + 4H₂O ⟶ MnO₄⁻ + 8H⁺ + 5e-

 

8. Multiply each half-reaction by a number to equalize the electrons transferred.

5 × [PbO₂+ 4H⁺ + 2e⁻ ⟶ Pb²⁺ + 2H₂O]

     2 × [Mn²⁺ + 4H₂O ⟶ MnO₄⁻ + 8H⁺ + 5e⁻]

9. Add the two half-reactions.

                          5PbO₂+ 20H⁺ + 10e⁻ ⟶ 5Pb²⁺ + 10H₂O

<u>                                    2Mn²⁺ + 8H₂O ⟶ 2MnO₄⁻ + 16H⁺ + 10e⁻                    </u>

5PbO₂ + 2Mn² + 8H₂O + 20H⁺ + 10e⁻⟶ 5Pb²⁺ + 2MnO₄⁻ + 10H₂O + 16H⁺ + 10e⁻

10. Cancel species that occur on each side of the equation

5PbO₂ + 2Mn² + <u>8H₂O</u> + <u>20H⁺</u> + <u>10e⁻</u> ⟶ 5Pb²⁺ + 2MnO₄⁻ + <u>10H₂O</u> + <u>16H⁺</u> + <u>10e⁻ </u>

becomes

5PbO₂ + 2Mn²⁺ + 4H⁺ ⟶ 5Pb²⁺ + 2MnO₄⁻ + 2H₂O

11. Add the missing spectator ions

5PbO₂ + 2Mn²⁺    + 4H⁺                              ⟶            5Pb²⁺   + 2MnO₄⁻ + 2H₂O

            + 2SO₄²⁻ + 4NO₃⁻ + 2H⁺ + 2NO₃⁻       +2SO₄²⁻ + 6NO₃⁻ + 2H⁺

becomes

5PbO₂ + 2MnSO₄ + 6HNO₃ ⟶ 2PbSO₄ + 3Pb(NO₃)₂ + 2HMnO₄ + 2H₂O

12. Check that all atoms are balanced.

\begin{array}{ccc}\textbf{Atom} & \textbf{On the left} & \textbf{On the right}\\\text{Pb} & 5 & 5\\\text{O} & 36 & 36\\\text{S} & 2 & 2\\\text{H} & 6 & 6\\\text{N} & 6 & 6\\\end{array}

Everything checks. The balanced equation is

5PbO₂ + 2MnSO₄ + 6HNO₃ ⟶ 2PbSO₄ + 3Pb(NO₃)₂ + 2HMnO₄ + 2H₂O

7 0
4 years ago
The data below refer to the following reaction: 2NO(g) + I2(g) 2NOI(g) Concentration (M) [NO] [I2] [NOI] Initial 2.0 4.0 1.0 Equ
anygoal [31]

Answer:

3.5 mol·L⁻¹  

Explanation:

1. Set up an ICE table.

\begin{array}{cccccc}\text{2NO} & + & \text{I}_{2} &\, \rightleftharpoons \, & \text{2NOI} & & \\ 2.0 &   &  4.0 &   & 1.0 &  & \\ -2x &   & -x &   & +2x &  &  \\ 2.0-2x &   & 4.0-x &   & 1.0+2x &  & \\\end{array}

2. Solve for x

The equilibrium concentration of NO is 1.0 mol·L⁻¹, so

       1.0 = 2.0 - 2x

2x + 1.0 = 2.0

        2x =  1.0

          x = 0.5

3. Calculate the equilibrium concentration of I₂

[I₂] = 4.0 - x = 4.0 - 0.5 = 3.5 mol·L⁻¹

4 0
3 years ago
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