1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
Ira Lisetskai [31]
3 years ago
13

Please help me equalize: PbO2 + MnSO4 + HNO3 = HMnO4 + PbSO4 + Pb(NO3)2 + H2O

Chemistry
1 answer:
Feliz [49]3 years ago
7 0

Answer:

5PbO₂ + 2MnSO₄ + 6HNO₃ ⟶ 2PbSO₄ + 3Pb(NO₃)₂ + 2HMnO₄+ 2H₂O

Explanation:

PbO₂ + MnSO₄ + HNO₃ ⟶ HMnO₄ + PbSO₄ + Pb(NO₃)₂ + H₂O

It will be easiest to balance this equation by the ion-electron method.

1. Write the ionic equation

PbO₂ + Mn²⁺ + SO₄²⁻ + H⁺ + NO₃⁻ ⟶ H⁺ + MnO₄⁻ + Pb²⁺ + SO₄²⁻ + Pb²⁺ + NO₃⁻ + H₂O

2. Eliminate H⁺, H₂O, and spectator ions

PbO₂ + Mn²⁺ ⟶ MnO₄⁻ + Pb²⁺  

3. Separate the skeleton equation into two half-reactions.

PbO₂  ⟶ Pb²⁺  

Mn²⁺ ⟶ MnO₄⁻

4. Balance all atoms other than H and O

Done

5. Balance O by adding water molecules to the deficient side

           PbO₂  ⟶ Pb²⁺ + 2H₂O

Mn²⁺ + 4H₂O ⟶ MnO₄⁻

6. Balance H by adding H⁺ ions to the deficient side.

  PbO₂+ 4H⁺ ⟶ Pb²⁺ + 2H₂O

Mn²⁺ + 4H₂O ⟶ MnO₄⁻ + 8H⁺

7. Balance charge by adding electrons to the deficient side.

PbO₂+ 4H⁺ + 2e⁻ ⟶ Pb²⁺ + 2H₂O

     Mn²⁺ + 4H₂O ⟶ MnO₄⁻ + 8H⁺ + 5e-

 

8. Multiply each half-reaction by a number to equalize the electrons transferred.

5 × [PbO₂+ 4H⁺ + 2e⁻ ⟶ Pb²⁺ + 2H₂O]

     2 × [Mn²⁺ + 4H₂O ⟶ MnO₄⁻ + 8H⁺ + 5e⁻]

9. Add the two half-reactions.

                          5PbO₂+ 20H⁺ + 10e⁻ ⟶ 5Pb²⁺ + 10H₂O

<u>                                    2Mn²⁺ + 8H₂O ⟶ 2MnO₄⁻ + 16H⁺ + 10e⁻                    </u>

5PbO₂ + 2Mn² + 8H₂O + 20H⁺ + 10e⁻⟶ 5Pb²⁺ + 2MnO₄⁻ + 10H₂O + 16H⁺ + 10e⁻

10. Cancel species that occur on each side of the equation

5PbO₂ + 2Mn² + <u>8H₂O</u> + <u>20H⁺</u> + <u>10e⁻</u> ⟶ 5Pb²⁺ + 2MnO₄⁻ + <u>10H₂O</u> + <u>16H⁺</u> + <u>10e⁻ </u>

becomes

5PbO₂ + 2Mn²⁺ + 4H⁺ ⟶ 5Pb²⁺ + 2MnO₄⁻ + 2H₂O

11. Add the missing spectator ions

5PbO₂ + 2Mn²⁺    + 4H⁺                              ⟶            5Pb²⁺   + 2MnO₄⁻ + 2H₂O

            + 2SO₄²⁻ + 4NO₃⁻ + 2H⁺ + 2NO₃⁻       +2SO₄²⁻ + 6NO₃⁻ + 2H⁺

becomes

5PbO₂ + 2MnSO₄ + 6HNO₃ ⟶ 2PbSO₄ + 3Pb(NO₃)₂ + 2HMnO₄ + 2H₂O

12. Check that all atoms are balanced.

\begin{array}{ccc}\textbf{Atom} & \textbf{On the left} & \textbf{On the right}\\\text{Pb} & 5 & 5\\\text{O} & 36 & 36\\\text{S} & 2 & 2\\\text{H} & 6 & 6\\\text{N} & 6 & 6\\\end{array}

Everything checks. The balanced equation is

5PbO₂ + 2MnSO₄ + 6HNO₃ ⟶ 2PbSO₄ + 3Pb(NO₃)₂ + 2HMnO₄ + 2H₂O

You might be interested in
Which of the following is not a feature of iron (III) oxide?
nataly862011 [7]

B for sure, considering iron oxide is just fancy for rust.

3 0
3 years ago
Read 2 more answers
Please solve quickly!!!!
ohaa [14]
6 ( tell me if you got it right)
3 0
3 years ago
The sun is 150 kilometers from earth.if you wanted to explain to friend how far is what would you say
jasenka [17]

Answer:

150 times 1000 is how many meters it is away from earth because kilo means 1000

Explanation:

easy metric conversions

5 0
3 years ago
What kind of properties can only be observed when a substance changes into a different substance?
Shkiper50 [21]
<h3>Answer:</h3><h2>Chemical properties</h2><h3>Explanation:</h3>

By its very definition, a chemical property is one which is exhibited as a result of a chemical reaction. This may happen during or after the reaction. This is because in a chemical reaction there is a transformation in the physical composition of the components and this directly affects its chemical properties.

4 0
3 years ago
By how much will the water temperature increases if 1046 J of heat energy are added. The specific heat of water is 4.184 J/g • °
Brilliant_brown [7]

Answer:

Option A

250 degrees Celcius

Explanation:

If 1046J of heat energy is added to water, the water will experience a rise in temperature, at a rate that is directly proportional to its specific heat capacity.

Mathematically, this can be seen as Q=C\Delta T

Where C = specific heat of water = 4.184 J/g • °C.

Q = heat energy = 1046 J

\Delta T =1046/4.148=250 degrees Celcius

Therefore, the increase in temperature that will be experienced, is for 250 degrees Celcius

8 0
2 years ago
Other questions:
  • You work in the special effects department of a movie studio. You are currently working on a superhero movie where the hero is v
    6·1 answer
  • Which of the following is a mixture Air, water, salt or sulfur
    12·1 answer
  • A rock weighing 26.0g is placed in a graduated cylinder displacing the volume from 13.2mL to 23.5mL what is the density in grams
    6·1 answer
  • When amino acids polymerize to make a protein, which of the following is produced as a byproduct?
    5·2 answers
  • How much water must be evaporated from 240 gallons of a 3 salt solution?
    15·1 answer
  • 65.5g of copper reacts with __g of oxygen to produce 81g copper(I) oxide
    6·1 answer
  • How many valence electrons does each of the following atoms have?
    9·1 answer
  • How many grams are KBr are needed to make a saturated solution in 100g of water at 30c
    10·1 answer
  • Please answer this if you do I will answer your questions!!
    8·2 answers
  • the coal sample being used in this experiment is assumed to have 3% sulfur in its composition. what percent of sulfate is presen
    14·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!