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adoni [48]
3 years ago
5

O tetraclorometano é um solvente muito utilizado na indústria de transformaç?o de produtos orgânicos ele é produzido pela reaç?o

química de coloraç?o total do metano conforme a equaç?o abaixo CH4+Cl2 >CCl4+HCl conhecendo as entalpias de formaç?o dos reagentes e produtos dados na tabela a seguir determine o valor de delta h para a reaç?o do cloro
Chemistry
1 answer:
Vlada [557]3 years ago
3 0

Answer:

ΔHr = -103,4 kcal/mol

Explanation:

<u>Using:</u>

<u>AH° (kcal/mol) </u>

<u>Metano (CH) </u>

<u>-17,9 </u>

<u>Cloro (CI) </u>

<u>tetraclorometano (CCI) </u>

<u>- 33,3 </u>

<u>Acido cloridrico (HCI) </u>

<u>-22</u>

It is possible to obtain the ΔH of a reaction from ΔH's of formation for each compound, thus:

ΔHr = (ΔH products - ΔH reactants)

For the reaction:

CH₄(g) + Cl₂(g) → CCl₄(g) + HCl(g)

The balanced reaction is:

CH₄(g) + 4Cl₂(g) → CCl₄(g) + 4HCl(g)

The ΔH's of formation for these compounds are:

ΔH CH₄(g): -17,9 kcal/mol

ΔH Cl₂(g): 0 kcal/mol

ΔH CCl₄(g): -33,3 kcal/mol

ΔH HCl(g): -22 kcal/mol

The ΔHr is:

-33,3 kcal/mol × 1 mol + -22 kcal/mol× 4 mol - (-17,9 kcal/mol × 1 mol + 0kcal/mol × 4mol)

<em>ΔHr = -103,4 kcal/mol</em>

<em></em>

I hope it helps!

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