Answer: Rotation occurs at single bonds that are sigma bonds. Rotational barrier is the amount of activation energy required to covert rotamer to another by rotation that occurs around the sigma bond(C-C single bond). Due to the presence of steric hindrance that is the nonbonding interaction effects the reactivity of ions and molecules, activation energy increases. So the rotational barrier in butenyl cation is high.
<span>XY4Z2-->Square planar (Electron domain geometry: Octahedral) sp3d2
XY4Z-->Seesaw (Electron domain geometry: Trigonal bipyramidal) sp3d
XY5Z-->Square pyramidal (Electron domain geometry: Octahedral) sp3d2
XY2Z3-->Linear (Electron domain geometry: Trigonal bipyramidal) sp3d
XY2Z-->Bent (Electron domain geometry: Trigonal planar) sp2
XY3Z-->Trigonal pyramidal (Electron domain geometry: Tetrahedral) sp3
XY2Z2-->Linear (Electron domain geometry: Tetrahedral) sp3
XY3Z2-->T shaped (Electron domain geometry: Trigonal bipryamidal) sp3d
XY2-->Linear (Electron domain geometry: Linear) sp
XY3 Trigonal planar (Electron geometry: Trigonal planar) sp2
XY4-->Tetrahedral (Electron domain geometry: tetrahedral) sp3
XY5-->Trigonal bipyramidal (Electron domain geometry: Trigonal bipyramidal) sp3d
XY6-->Octahedral (Electron domain geometry: Octahedral) sp3d2</span>
Answer:
<h3>the equilibrium constant of the decomposition of hydrogen bromide is 0.084</h3>
Explanation:
Amount of HBr dissociated
2HBr(g) ⇆ H2(g) + Br2(g)
Initial Changes 2.15 0 0 (mol)
- 0.789 + 0.395 + 0.395 (mol)
At equilibrium 1.361 0.395 0.395 (mole)
Concentration 1.361 / 1 0.395 / 1 0.395 / 1
at equilibrium (mole/L)
![K_c=\frac{[H_2][Br_2]}{[HBr]^2} \\\\=\frac{(0.395)(0.395)}{(1.361)^2} \\\\=\frac{0.156025}{1.852321} \\\\=0.084](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BH_2%5D%5BBr_2%5D%7D%7B%5BHBr%5D%5E2%7D%20%5C%5C%5C%5C%3D%5Cfrac%7B%280.395%29%280.395%29%7D%7B%281.361%29%5E2%7D%20%5C%5C%5C%5C%3D%5Cfrac%7B0.156025%7D%7B1.852321%7D%20%5C%5C%5C%5C%3D0.084)
<h3>Therefore, the equilibrium constant of the decomposition of hydrogen bromide is 0.084</h3>
Hope this helps
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