Answer:
<em>a) 607.95 J</em>
<em>b) 0 J</em>
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Explanation:
a) Initial volume = 1 L = 0.001 m^3
final volume = 4 L = 0.004 m^3
pressure = 2 atm = 202650 Pa (1 atm = 101325 Pa)
work done by the gas on the environment = PΔV
P is the pressure = 101325 Pa
ΔV is the change in volume from the initial volume to the final volume
ΔV = 0.004 m^3 - 0.001 m^3 = 0.003 m^3
work done by the gas = 202650 x 0.003 = <em>607.95 J</em>
b) If the gas is cooled at constant volume, then the gas does no work. For a gas to do work, there must be a change in its volume.
Therefore the work done in cooling at constant volume until pressure falls to 1.5 atm = <em>0 J</em>