3rd one sorry if it’s wrong
1. 0.33 M
2. 0.278 M
<h3>Further explanation</h3>
Molarity is a way to express the concentration of the solution
Molarity shows the number of moles of solute in every 1 liter of solute or mmol in each ml of solution

Where
M = Molarity
n = Number of moles of solute
V = Volume of solution
1. 0.350 mol of NaOH in 1.05 L of solution.
n=0.35
V=1.05 L
Molarity :

2. 14.3 g of NaCl in 879 mL of solution.
mol NaCl(MW=58.5 g/mol) :

Molarity :

Answer : The molar heat of solution of KCl is, 17.19 kJ/mol
Explanation :
First we have to calculate the heat of solution.

where,
q = heat produced = ?
c = specific heat capacity of water = 
= change in temperature = 0.360 K
Now put all the given values in the above formula, we get:


Now we have to calculate the molar heat solution of KCl.

where,
= enthalpy change = ?
q = heat released = 460.8 J
m = mass of
= 2.00 g
Molar mass of
= 74.55 g/mol

Now put all the given values in the above formula, we get:


Therefore, the molar heat of solution of KCl is, 17.19 kJ/mol
Answer is: unsaturated.
Solubility of potassium chlorate on 70°C is approximately 30 grams in 100 grams of water.
Solubility of potassium chlorate on 70°C is approximately 10 grams in 100 grams of water.
So if dissolve 15 g of potassium chlorate in 201 g of water, there is less salt than it solubility and solution is unsaturated.