The correct option is (b)
NaNH2 is an effective base. It can be a good nucleophile in the few situations where its strong basicity does not have negative side effects. It is employed in elimination reactions as well as the deprotonation of weak acids.Alkynes, alcohols, and a variety of other functional groups with acidic protons, such as esters and ketones, will all be deprotonated by NaNH2, a powerful base.Alkynes are deprotonated with NaNH2 to produce what are known as "acetylide" ions. These ions are powerful nucleophiles that can react with alkyl halides to create carbon-carbon bonds and add to carbonyls in an addition reaction.Acid/base and nucleophilic substitution are the two types of reactions.Using the right base, terminal alkynes can be deprotonated to produce a carbanion.A good C is the acetylide carbanion.The acetylide carbanion can undergo nucleophilic substitution reactions because it is a potent C nucleophile. (often SN2) with 1 or 2 alkyl halides with electrophilic C to create an internal alkyne (Cl, Br, or I).Elimination is more likely to occur with 3-alkyl halides.It is possible to swap either one or both of the terminal H atoms in ethylene (acetylene) to create monosubstituted (R-C-C-H) and symmetrical (R = R') or unsymmetrical (R not equal to R') disubstituted alkynes (R-C-C-R').
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Here we will use the general formula of Nernst equation:
Ecell = E°Cell - [(RT/nF)] *㏑Q
when E cell is cell potential at non - standard state conditions
E°Cell is standard state cell potential = - 0.87 V
and R is a constant = 8.314 J/mol K
and T is the temperature in Kelvin = 73 + 273 = 346 K
and F is Faraday's constant = 96485 C/mole
and n is the number of moles of electron transferred in the reaction=2
and Q is the reaction quotient for the reaction
SO42-2(aq) + 4H+(aq) +2Br-(aq) ↔ Br2(aq) + SO2(g) +2H2O(l)
so by substitution :
0 = -0.87 - [(8.314*346K)/(2* 96485)*㏑Q → solve for Q
∴ Q = 4.5 x 10^-26
When ketone is reacted with phosphorous pentachloride, chlorination takes place at the carbonyl carbon with substitution of the oxygen atom to give a geminal dichloride (with 2 Cl atoms on same carbon) according to the following equation:
so we can say that acetone is converted into 2,2-dichloropropane by action of PCl₅
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A mineral occurs naturally, meaning that even though there are artificial substances that might be described as mineral-like they are not minerals
<span>electron, I believe.
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