The first heart chamber that the dye would enter is right atrium.
This will be followed by
left ventricle
right ventricle
left atrium
coronary valve
Ice actually has a very different structure than liquid water, in that the molecules align themselves in a regular lattice rather than more randomly as in the liquid form. It happens that the lattice arrangement allows water molecules to be more spread out than in a liquid, and, thus, ice is less dense than water.
Producers are primary consumers and it gets 10 %