Raising of the boiling point is a colligative property. That means that it depends on the number of particles dissolved. The greater the number of particles the greater the increase in the boiling point. So, you can compare the effect of these solutes in the increase of the boiling point by writing the chemical equations and comparing the number of particles dissolved: 1)ionic lithium chloride, LiCl(s) --> Li(+) + Cl (-) => 2 ions; 2) ionic sodium chloride, NaCl(s) --> Na(+) + Cl(-) => 2 ions; 3) molecular sucrose, C12H22O11 (s) ---> C12H22O11(aq) => 1 molecule; 4) ionic phosphate, Na3PO4 --> 3Na(+) + PO4 (3-) => 4 ions; 5) ionic magnesium bromide, MgBr2 --> Mg(2+) + 2 Br(-) => 3 ions. <span>So, ionic phosphate produces the greatest number of particles and it will cause the greatest increase of the boiling point.</span><span />
write an equation to represent the oxidation of an alcohol.
identify the reagents that may be used to oxidize a given alcohol.
identify the specific reagent that is used to oxidize primary alcohols to aldehydes rather than to carboxylic acids.
identify the product formed from the oxidation of a given alcohol with a specified oxidizing agent.
identify the alcohol needed to prepare a given aldehyde, ketone or carboxylic acid by simple oxidation.
write a mechanism for the oxidation of an alcohol using a chromium(VI) reagent.
The reading mentions that pyridinium chlorochromate (PCC) is a milder version of chromic acid that is suitable for converting a primary alcohol into an aldehyde without oxidizing it all the way to a carboxylic acid. This reagent is being replaced in laboratories by Dess‑Martin periodinane (DMP), which has several practical advantages over PCC, such as producing higher yields and requiring less rigorous reaction conditions. DMP is named after Daniel Dess and James Martin, who developed it in 1983.
This page looks at the oxidation of alcohols using acidified sodium or potassium dichromate(VI) solution. This reaction is used to make aldehydes, ketones and carboxylic acids, and as a way of distinguishing between primary, secondary and tertiary alcohols.
Oxidizing the different types of alcohols
The oxidizing agent used in these reactions is normally a solution of sodium or potassium dichromate(VI) acidified with dilute sulfuric acid. If oxidation occurs, the orange solution containing the dichromate(VI) ions is reduced to a green solution containing chromium(III) ions. The electron-half-equation for this reaction is
Cr2O2−7+14H++6e−→2Cr3++7H2O
C2H4 is oxidized and O2 is reduced in both reactions.
<h3>What is oxidation/reduction?</h3>
Oxidation is defined in several ways. Some of the definitions are:
- The addition of oxygen or removal of hydrogen
- Increase in the oxidation number of atoms
- Addition of electronegative or the removal of electropositive elements
Reduction, on the other hand, is defined as:
- Removal of oxygen or addition of hydrogen
- Decrease in the oxidation number of atoms
- Addition of electropositive elements or the removal of electronegative elements.
In the two reactions, oxygen is being added to C2H4. Thus, C2H4 is being oxidized.
The oxidizing agent is O2. In oxidation reactions, the oxidizing agents usually get reduced. Thus, O2 is reduced in both reactions.
More on oxidation and reduction can be found here: brainly.com/question/3867774
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Answer:
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