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Sphinxa [80]
3 years ago
10

The reaction of cr2+(aq) with cr2o2−7(aq) in acid solution to form cr3+(aq). calculate δg∘rxn.

Chemistry
2 answers:
Nat2105 [25]3 years ago
8 0
The reaction is:
6 Cr²⁺ + Cr₂O₇²⁻ + 14 H⁺ → 8 Cr³⁺ + 7 H₂O

E₀ = 1.33 - (-0.5) = 1.83 V

ΔG = - n f E₀
      = - 6 * 96485  * 1.83
      = - 1059405.3 J / mol
      = - 1059.4 kJ / mol
KiRa [710]3 years ago
4 0

Answer:

The correct answer is -1059.45 kJ.

Explanation:

The balanced equation is:

6Cr₂⁺ + Cr₂O₇²⁻ + 14H⁺ ⇒ 8Cr₃⁺ + 7H₂O

In the mentioned reaction 6 electrons are transferred

By calculating Ecell with the use of reduction potential of each cell:

Ecell = Eox + Ered

Ered = 0.50V

Eox = -Ered = -(-0.50V) = 0.50V

Ered = 1.33V

Ecell = 0.50V + 1.33V

Ecell = 1.83V

Now in order to calculate ΔG

n = 6, Faraday constant (f) = 9.68470 × 10⁴ = 96847 C mol⁻¹

ΔG = -nFE

ΔG = -6 × 96487 C mol-1 × 1.83V

ΔG = -1059.42 KJ

The relation between ΔG and ΔG°rxn

ΔG = ΔG° + RTlnQ

Under the standard condition Q = 1 and ΔG = ΔG°

Thus,

ΔG°rxn = ΔG = -1059.42 KJ

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ollegr [7]
The reaction is 
Zn(s) + 2MnO₂(s) + H₂O(l) ⟶ Zn(OH)₂(s) + Mn₂O₃(s)

The reactants are Zn(s) and MnO₂(s) while Zn(OH)₂(s) and Mn₂O₃(s) products.

Let's see the oxidation state of each compound.
sum of the o.s. of the each element of compound = charge of the compound

O.s of O = -2
O.s of OH⁻ = -1

O.s of Zn(s) = 0

O.s of Mn in MnO₂(s) = x
         x + (-2) * 2 = 0
             x            = +4


O.s of Zn in Zn(OH)₂(s) = a
          a + (-1) * 2 = 0
                 a         = +2

O.s of Mn in Mn₂O₃(s) = b
          2*b + (-2) * 3 = b
                         2b   = 6
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Since the O.s is reduced in Mn from +4 to +3, the reduced species is Mn₂O₃(s).

8 0
3 years ago
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If kb for nx3 is 4.0×10−6, what is the poh of a 0.175 m aqueous solution of nx3?
Elena-2011 [213]
<h3><u>Answer;</u></h3>

pOH = 3.08

<h3><u>Explanation;</u></h3>

NX3 + H2O <----> NHX3+ + OH-  

Kb = 4.0 x 10^-6

Kb = c(NH₄⁺) · c(OH⁻) ÷ c(NH₃).

c(NH₄⁺) = c(OH⁻) = x.

x² = Kb · c(NH₃)

x² = 4.0 × 10⁻⁶ × 0.175 = 7.0 × 10⁻⁷.

x = c(OH⁻) = √(7.0 × 10⁻⁷)

    = 8.367 × 10⁻⁴

pOH = -log(c(OH⁻))

        =- log ( 8.367 × 10⁻⁴)

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Answer:

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