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Consider the following reaction: CO2(g)+CCl4(g)⇌2COCl2(g) Calculate ΔG for this reaction at25 ∘C under these conditions: PCO2PCC

Salsk061 [2.6K]

<u>Answer:</u> The $\Delta G$ for the reaction is 54.6 kJ/mol

<u>Explanation:</u>

For the given balanced chemical equation:

$CO_2(g)+CCl_4(g)\rightleftharpoons 2COCl_2(g)$

We are given:

$\Delta G^o_f_{CO_2}=-394.4kJ/mol\\\Delta G^o_f_{CCl_4}=-62.3kJ/mol\\\Delta G^o_f_{COCl_2}=-204.9kJ/mol$

To calculate $\Delta G^o_{rxn}$ for the reaction, we use the equation:

$\Delta G^o_{rxn}=\sum [n\times \Delta G_f(product)]-\sum [n\times \Delta G_f(reactant)]$

For the given equation:

$\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(COCl_2)})]-[(1\times \Delta G^o_f_{(CO_2)})+(1\times \Delta G^o_f_{(CCl_4)})]$

Putting values in above equation, we get:

$\Delta G^o_{rxn}=[(2\times (-204.9))-((1\times (-394.4))+(1\times (-62.3)))]\\\Delta G^o_{rxn}=46.9kJ=46900J$

Conversion factor used = 1 kJ = 1000 J

The expression of $K_p$ for the given reaction:

$K_p=\frac{(p_{COCl_2})^2}{p_{CO_2}\times p_{CCl_4}}$

We are given:

$p_{COCl_2}=0.760atm\\p_{CO_2}=0.140atm\\p_{CCl_4}=0.180atm$

Putting values in above equation, we get:

$K_p=\frac{(0.760)^2}{0.140\times 0.180}\\\\K_p=22.92$

To calculate the Gibbs free energy of the reaction, we use the equation:

$\Delta G=\Delta G^o+RT\ln K_p$

where,

$\Delta G$ = Gibbs' free energy of the reaction = ?

$\Delta G^o$ = Standard gibbs' free energy change of the reaction = 46900 J

R = Gas constant = $8.314J/K mol$

T = Temperature = $25^oC=[25+273]K=298K$

$K_p$ = equilibrium constant in terms of partial pressure = 22.92

Putting values in above equation, we get:

$\Delta G=46900J+(8.314J/K.mol\times 298K\times \ln(22.92))\\\\\Delta G=54659.78J/mol=54.6kJ/mol$

Hence, the $\Delta G$ for the reaction is 54.6 kJ/mol

7 0

3 years ago

What happens to iron when iron oxide becomes elemental iron?

Ilya [14]

The appropriate response is Reduction. It is a chemical reaction that includes the picking up of electrons. It alludes to the side that acknowledges electrons. At the point when iron responds with oxygen, it frames a concoction called rust. In that case, the iron is oxidized and the oxygen is lessened.

6 0

4 years ago

Read 2 more answers

In this reaction, _____.

ella [17]

Answer:

AB + CD ----> AC + BD

Explanation:

If you think this reaction:

AB + CD ----> AC + BD

(Reactants) (Products)

All the statements are true.